Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Visible-Light-Promoted Metal- and Photocatalyst-Free Reactions between Arylglyoxylic Acids and Tetraalkylthiuram Disulfides: Synthesis of α-Ketoamides
AU - Sarkar, Subhankar
AU - Pal, Satyajit
AU - Mukherjee, Anindita
AU - Santra, Sougata
AU - Zyryanov, Grigory
AU - Majee, Adinath
N1 - A.M. and S.S. acknowledge financial support from the CSIR-Major Research Project (ref no. 02(0383)/19/EMR-II). The authors are thankful to the DST-FIST and UGC-SAP program of the Department of Chemistry, Visva-Bharati. G.V.Z. and S.S. also acknowledge financial support from the Ministry of Science and Higher Education of the Russian Federation (ref # 075-15-2022-1118 dated 29 June 2022).
PY - 2024
Y1 - 2024
N2 - A convenient and new synthetic approach has been developed for the oxidative cross-coupling of the C-N bond through the reaction between arylglyoxylic acids and tetraalkylthiuram disulfides. The reaction proceeds under ambient air at room temperature in the presence of visible light. This reaction offers a metal-, base-, photocatalyst-, and solvent-free synthesis of various α-ketoamides with moderate to excellent yields via the radical pathway. In addition, this protocol demonstrates the potential application of a gram-scale synthesis. © 2024 American Chemical Society.
AB - A convenient and new synthetic approach has been developed for the oxidative cross-coupling of the C-N bond through the reaction between arylglyoxylic acids and tetraalkylthiuram disulfides. The reaction proceeds under ambient air at room temperature in the presence of visible light. This reaction offers a metal-, base-, photocatalyst-, and solvent-free synthesis of various α-ketoamides with moderate to excellent yields via the radical pathway. In addition, this protocol demonstrates the potential application of a gram-scale synthesis. © 2024 American Chemical Society.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85183090985
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001157571500001
U2 - 10.1021/acs.joc.3c02081
DO - 10.1021/acs.joc.3c02081
M3 - Article
VL - 89
SP - 1473
EP - 1482
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 3
ER -
ID: 52961149