Результаты исследований: Вклад в журнал › Обзорная статья › Рецензирование
Результаты исследований: Вклад в журнал › Обзорная статья › Рецензирование
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TY - JOUR
T1 - Recent advances in the chemistry of two-carbon nitro-containing synthetic equivalents
AU - Lyapustin, D. N.
AU - Fedotov, V. V.
AU - Ulomsky, E. N.
AU - Rusinov, V. L.
AU - Chupakhin, O. N.
N1 - This work was funded by the Ministry of Science and the Higher Education of the Russian Federation [State contract No. FEUZ-2023-0021 (H687/42fi.325/23)].
PY - 2023
Y1 - 2023
N2 - To date, nitro-containing compounds form one of the most important classes of organic compounds. The chemistry of these molecules attracts attention primarily due to their use as high-energy reagents and drugs. Also, the introduction of a nitro group is a popular synthetic strategy for constructing new organic molecules. The present review summarizes the latest research findings of compounds bearing a nitro group on a two-carbon moiety such as aminonitroethylenes, alpha,alpha-bis(alkyl-sulfanyl)nitroalkenes and their amino derivatives, alpha-nitroketones, alkyl nitroacetates and nitroacetonitrile. The literature data are systematized according to the type of chemical reactions such as reactions between nucleophiles and electrophiles, various cyclization reactions, reactions at the C-H bond, etc. The reactivities of the said nitro compounds and the conditions of chemical transformations are compared to assess the prospects of their application.
AB - To date, nitro-containing compounds form one of the most important classes of organic compounds. The chemistry of these molecules attracts attention primarily due to their use as high-energy reagents and drugs. Also, the introduction of a nitro group is a popular synthetic strategy for constructing new organic molecules. The present review summarizes the latest research findings of compounds bearing a nitro group on a two-carbon moiety such as aminonitroethylenes, alpha,alpha-bis(alkyl-sulfanyl)nitroalkenes and their amino derivatives, alpha-nitroketones, alkyl nitroacetates and nitroacetonitrile. The literature data are systematized according to the type of chemical reactions such as reactions between nucleophiles and electrophiles, various cyclization reactions, reactions at the C-H bond, etc. The reactivities of the said nitro compounds and the conditions of chemical transformations are compared to assess the prospects of their application.
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000991722500003
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85162178506
U2 - 10.57634/RCR5077
DO - 10.57634/RCR5077
M3 - Review article
VL - 92
JO - Russian Chemical Reviews
JF - Russian Chemical Reviews
SN - 0036-021X
IS - 4
M1 - RCR5077
ER -
ID: 40038571