Recent advances in the chemistry of two-carbon nitro-containing synthetic equivalents

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Recent advances in the chemistry of two-carbon nitro-containing synthetic equivalents. / Lyapustin, D. N.; Fedotov, V. V.; Ulomsky, E. N. et al.
In: Russian Chemical Reviews, Vol. 92, No. 4, RCR5077, 2023.

Research output: Contribution to journal › Review article › peer-review

BibTeX

@article{74e824b3d56b4e1a8da6d2a94704ce06,

title = "Recent advances in the chemistry of two-carbon nitro-containing synthetic equivalents",

abstract = "To date, nitro-containing compounds form one of the most important classes of organic compounds. The chemistry of these molecules attracts attention primarily due to their use as high-energy reagents and drugs. Also, the introduction of a nitro group is a popular synthetic strategy for constructing new organic molecules. The present review summarizes the latest research findings of compounds bearing a nitro group on a two-carbon moiety such as aminonitroethylenes, alpha,alpha-bis(alkyl-sulfanyl)nitroalkenes and their amino derivatives, alpha-nitroketones, alkyl nitroacetates and nitroacetonitrile. The literature data are systematized according to the type of chemical reactions such as reactions between nucleophiles and electrophiles, various cyclization reactions, reactions at the C-H bond, etc. The reactivities of the said nitro compounds and the conditions of chemical transformations are compared to assess the prospects of their application.",

author = "Lyapustin, {D. N.} and Fedotov, {V. V.} and Ulomsky, {E. N.} and Rusinov, {V. L.} and Chupakhin, {O. N.}",

note = "This work was funded by the Ministry of Science and the Higher Education of the Russian Federation [State contract No. FEUZ-2023-0021 (H687/42fi.325/23)].",

year = "2023",

doi = "10.57634/RCR5077",

language = "English",

volume = "92",

journal = "Russian Chemical Reviews",

issn = "0036-021X",

publisher = "Turpion Ltd.",

number = "4",

}

RIS

TY - JOUR

T1 - Recent advances in the chemistry of two-carbon nitro-containing synthetic equivalents

AU - Lyapustin, D. N.

AU - Fedotov, V. V.

AU - Ulomsky, E. N.

AU - Rusinov, V. L.

AU - Chupakhin, O. N.

N1 - This work was funded by the Ministry of Science and the Higher Education of the Russian Federation [State contract No. FEUZ-2023-0021 (H687/42fi.325/23)].

PY - 2023

Y1 - 2023

N2 - To date, nitro-containing compounds form one of the most important classes of organic compounds. The chemistry of these molecules attracts attention primarily due to their use as high-energy reagents and drugs. Also, the introduction of a nitro group is a popular synthetic strategy for constructing new organic molecules. The present review summarizes the latest research findings of compounds bearing a nitro group on a two-carbon moiety such as aminonitroethylenes, alpha,alpha-bis(alkyl-sulfanyl)nitroalkenes and their amino derivatives, alpha-nitroketones, alkyl nitroacetates and nitroacetonitrile. The literature data are systematized according to the type of chemical reactions such as reactions between nucleophiles and electrophiles, various cyclization reactions, reactions at the C-H bond, etc. The reactivities of the said nitro compounds and the conditions of chemical transformations are compared to assess the prospects of their application.

AB - To date, nitro-containing compounds form one of the most important classes of organic compounds. The chemistry of these molecules attracts attention primarily due to their use as high-energy reagents and drugs. Also, the introduction of a nitro group is a popular synthetic strategy for constructing new organic molecules. The present review summarizes the latest research findings of compounds bearing a nitro group on a two-carbon moiety such as aminonitroethylenes, alpha,alpha-bis(alkyl-sulfanyl)nitroalkenes and their amino derivatives, alpha-nitroketones, alkyl nitroacetates and nitroacetonitrile. The literature data are systematized according to the type of chemical reactions such as reactions between nucleophiles and electrophiles, various cyclization reactions, reactions at the C-H bond, etc. The reactivities of the said nitro compounds and the conditions of chemical transformations are compared to assess the prospects of their application.

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000991722500003

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85162178506

U2 - 10.57634/RCR5077

DO - 10.57634/RCR5077

M3 - Review article

VL - 92

JO - Russian Chemical Reviews

JF - Russian Chemical Reviews

SN - 0036-021X

IS - 4

M1 - RCR5077

ER -

ID: 40038571