Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Triazole-Containing Polymers: Solubility and Thermodynamic Behavior in Solutions
AU - Tsypina, Natalya A.
AU - Kizhnyaev, Valerii N.
AU - Adamova, L. V.
PY - 2003
Y1 - 2003
N2 - The thermodynamics of the interaction of various triazole-containing polymers with different liquids was studied. For all the studied systems, the dissolution and swelling of poly(vinyltriazoles) are characterized by negative values of the Gibbs energy, enthalpy, and entropy of mixing due to the amphoteric character of a triazole moiety. It was shown that the solubility of poly(vinyltriazoles) and the thermodynamic parameters of the polymer-solvent interaction depend on the mutual arrangement of nitrogen atoms in the triazole substituent.
AB - The thermodynamics of the interaction of various triazole-containing polymers with different liquids was studied. For all the studied systems, the dissolution and swelling of poly(vinyltriazoles) are characterized by negative values of the Gibbs energy, enthalpy, and entropy of mixing due to the amphoteric character of a triazole moiety. It was shown that the solubility of poly(vinyltriazoles) and the thermodynamic parameters of the polymer-solvent interaction depend on the mutual arrangement of nitrogen atoms in the triazole substituent.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=0344736679
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000186526700013
M3 - Article
VL - 45
SP - 1035
EP - 1039
JO - Polymer Science - Series A
JF - Polymer Science - Series A
SN - 0965-545X
IS - 10
ER -
ID: 44363077