Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - The GdMn1-Ru Si compounds cassette for magnetocaloric nitrogen liquefaction
AU - Platonov, S.
AU - Kuchin, A.
AU - Volegov, A.
AU - Gaviko, V.
AU - Mukhachev, R.
AU - Lukoyanov, A.
AU - Yakovleva, M.
N1 - X-ray diffraction and magnetometric measurements were conducted on equipment of the Collaborative Access Center \u201CTesting Center of Nanotechnologies and Advanced Materials\u201D of the Institute of Metal Physics (Ural Branch, Russian Academy of Sciences). The results of sections 1, 2, 3 were obtained within the grant of the Russian Science Foundation (project No. 18-72-10098, https://rscf.ru/en/project/18-72-10098/ ). The results of sections 3.1 and 4 were obtained within the state assignment of Ministry of Science and Higher Education of the Russian Federation (themes \u201CMagnet\u201D No. 122021000034-9 and \u201CElectron\u201D No. 122021000039-4).
PY - 2024
Y1 - 2024
N2 - New intermetallic compounds GdMn1-xRuxSi, x = 0–1 with a tetragonal structure of the CeFeSi-type (P4/nmm) have been synthesized. For GdMn1-xRuxSi, Curie temperature TC drops sharply from 320 K (x = 0) to 78.3 K (x = 1), while the magnetocaloric effect varies from 1.84 J/kgK (x = 0) to 4.94 J/kgK (x = 1) with a change in the magnetic field of 0–17 kOe. Thus, the GdMn1-xRuxSi magnetic refrigeration compounds operate at temperatures from 320 K to 78.3 K, close to the nitrogen liquefaction temperature of 77.4 K. Therefore, the GdMn1-xRuxSi system, where x ranges from 0 to 1, could be of practical interest for nitrogen liquefaction, provided that these alloys are assembled into a cassette with a single large refrigerant capacity. The electronic structure and magnetic moments of the GdMn1-xRuxSi intermetallic compounds were calculated using the DFT + U theoretical method. © 2024 Elsevier B.V.
AB - New intermetallic compounds GdMn1-xRuxSi, x = 0–1 with a tetragonal structure of the CeFeSi-type (P4/nmm) have been synthesized. For GdMn1-xRuxSi, Curie temperature TC drops sharply from 320 K (x = 0) to 78.3 K (x = 1), while the magnetocaloric effect varies from 1.84 J/kgK (x = 0) to 4.94 J/kgK (x = 1) with a change in the magnetic field of 0–17 kOe. Thus, the GdMn1-xRuxSi magnetic refrigeration compounds operate at temperatures from 320 K to 78.3 K, close to the nitrogen liquefaction temperature of 77.4 K. Therefore, the GdMn1-xRuxSi system, where x ranges from 0 to 1, could be of practical interest for nitrogen liquefaction, provided that these alloys are assembled into a cassette with a single large refrigerant capacity. The electronic structure and magnetic moments of the GdMn1-xRuxSi intermetallic compounds were calculated using the DFT + U theoretical method. © 2024 Elsevier B.V.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85192067880
U2 - 10.1016/j.physb.2024.416060
DO - 10.1016/j.physb.2024.416060
M3 - Article
VL - 685
JO - Physica B: Condensed Matter
JF - Physica B: Condensed Matter
SN - 0921-4526
M1 - 416060
ER -
ID: 56632509