Synthesis of indium(3) chloride complexes with crown ethers and crystal structure of InCl3·2H2O·15C5 and InCl3·3H2O·18C6

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Synthesis of indium(3) chloride complexes with crown ethers and crystal structure of InCl3·2H2O·15C5 and InCl3·3H2O·18C6. / Strel'tsova, N. R. ; Ivanov, M. G.; Vashchenko, S. D. и др.
в: Координационная химия, Том 17, № 5, 1991, стр. 646-651.

Результаты исследований: Вклад в журнал › Статья › Рецензирование

BibTeX

@article{634945d65aa14bdab7f7d20ea829a7d8,

title = "Synthesis of indium(3) chloride complexes with crown ethers and crystal structure of InCl3·2H2O·15C5 and InCl3·3H2O·18C6",

abstract = "Complexes of INCl3 with crown ethers (12-crown-4, 15-crown-5 and 18-crown-6) of InCl3·nH2O·L and (InCl3)m·L compositions were synthesized. It is shown that elevation of temperature during synthesis of InCl3 complexes with crown ethers leads to formation and separation of anhydrous complexes from organic aqueous solutions. X-Ray structural investigation into InCl3·2H2O·15C5 (1) and InCl3·3H2O·18C6 (2) enabled to establish that their structure was similar to sandwich one, where inorganic InCl3·nH2O complex, connected with crown ethers by H-bonds, was located between macrocycle molecules. Lattice parameters for 1 : a=8.446, b=8.607, c=13.822 A; γ=70,02 deg, sp. gr. P21; for 2 : a=10.838, b=14.812, c=13,719 A, sp. gr. Cmcm/",

author = "Strel'tsova, {N. R.} and Ivanov, {M. G.} and Vashchenko, {S. D.} and Belsky, {Vitalii K.} and Kalinichenko, {I. I.}",

year = "1991",

language = "Русский",

volume = "17",

pages = "646--651",

journal = "Координационная химия",

issn = "0132-344X",

publisher = "Издательство {"}Наука{"}",

number = "5",

}

RIS

TY - JOUR

T1 - Synthesis of indium(3) chloride complexes with crown ethers and crystal structure of InCl3·2H2O·15C5 and InCl3·3H2O·18C6

AU - Strel'tsova, N. R.

AU - Ivanov, M. G.

AU - Vashchenko, S. D.

AU - Belsky, Vitalii K.

AU - Kalinichenko, I. I.

PY - 1991

Y1 - 1991

N2 - Complexes of INCl3 with crown ethers (12-crown-4, 15-crown-5 and 18-crown-6) of InCl3·nH2O·L and (InCl3)m·L compositions were synthesized. It is shown that elevation of temperature during synthesis of InCl3 complexes with crown ethers leads to formation and separation of anhydrous complexes from organic aqueous solutions. X-Ray structural investigation into InCl3·2H2O·15C5 (1) and InCl3·3H2O·18C6 (2) enabled to establish that their structure was similar to sandwich one, where inorganic InCl3·nH2O complex, connected with crown ethers by H-bonds, was located between macrocycle molecules. Lattice parameters for 1 : a=8.446, b=8.607, c=13.822 A; γ=70,02 deg, sp. gr. P21; for 2 : a=10.838, b=14.812, c=13,719 A, sp. gr. Cmcm/

AB - Complexes of INCl3 with crown ethers (12-crown-4, 15-crown-5 and 18-crown-6) of InCl3·nH2O·L and (InCl3)m·L compositions were synthesized. It is shown that elevation of temperature during synthesis of InCl3 complexes with crown ethers leads to formation and separation of anhydrous complexes from organic aqueous solutions. X-Ray structural investigation into InCl3·2H2O·15C5 (1) and InCl3·3H2O·18C6 (2) enabled to establish that their structure was similar to sandwich one, where inorganic InCl3·nH2O complex, connected with crown ethers by H-bonds, was located between macrocycle molecules. Lattice parameters for 1 : a=8.446, b=8.607, c=13.822 A; γ=70,02 deg, sp. gr. P21; for 2 : a=10.838, b=14.812, c=13,719 A, sp. gr. Cmcm/

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=A1991FZ21900009

M3 - Статья

VL - 17

SP - 646

EP - 651

JO - Координационная химия

JF - Координационная химия

SN - 0132-344X

IS - 5

ER -

ID: 55103240