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Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Second Example of a Cubane-Like Nickel(II) Complex in a Series of N-Derivatives of Taurine
AU - Zemlyakova, E. O.
AU - Khamidullina, L. A.
AU - Puzyrev, I. S.
AU - Tobysheva, P. D.
AU - Petrova, Yu. S.
AU - Neudachina, L. K.
AU - Slepukhin, P. A.
AU - Pestov, A. V.
N1 - This study was supported by the Russian Science Foundation, project no. 22-26-20068; https://rscf.ru/project/22-26-20068.
PY - 2023/7/1
Y1 - 2023/7/1
N2 - A new homometallic cubane-like nickel(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid [Ni4L4(OH)4]·2H2O (I) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2211359). In crystals of the complex, the metallocenters are joined into tetrahedra with the Ni…Ni distances (3.144–3.201 Å) supplemented to cubanes by the μ3-bridging oxygen atoms of the hydroxy groups. The coordination environment of each metallocenter is a distorted octahedron. The ligand is deprotonated, exists in the facial conformation, and performs the tridentate function to form two six-membered conjugated chelate cycles.
AB - A new homometallic cubane-like nickel(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid [Ni4L4(OH)4]·2H2O (I) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2211359). In crystals of the complex, the metallocenters are joined into tetrahedra with the Ni…Ni distances (3.144–3.201 Å) supplemented to cubanes by the μ3-bridging oxygen atoms of the hydroxy groups. The coordination environment of each metallocenter is a distorted octahedron. The ligand is deprotonated, exists in the facial conformation, and performs the tridentate function to form two six-membered conjugated chelate cycles.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85163819683
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001022878000007
U2 - 10.1134/S1070328423600195
DO - 10.1134/S1070328423600195
M3 - Article
VL - 49
SP - 446
EP - 452
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 7
ER -
ID: 41593404