The process of leaching of lead cakes of zinc production in a complexing solvent—trilon B, which makes it possible to selectively extract lead into the solution—is studied with the use of mathematical modeling of the experiment. Its optimum conditions—pH, liquid-to-solid ratio within pulp, and temperature—are determined. The developed flow chart of cake processing provides zinc removal as a single product, recycling of zinc to the basic production, and reduction of current expenditure due to solvent regeneration.