Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins
AU - Grzhegorzhevskii, Kirill
AU - Haouas, Mohamed
AU - Lion, Maxence
AU - Vashurin, Arthur
AU - Denikaev, Andrey
AU - Marfin, Yuriy
AU - Kim, Grigoriy
AU - Falaise, Clément
AU - Cadot, Emmanuel
PY - 2022
Y1 - 2022
N2 - Noncovalent ionic interactions between nanosized Keplerate-type capsules {Mo132} and tetra-cationic porphyrins have been investigated in aqueous solution using small-angle X-ray scattering, 1H NMR and photophysical methods. These complementary multiscale methods reveal the formation of large hybrid oligomers built from a short-range organization in which the cationic porphyrin is glued onto the large POM surface. The local structuring appears to be strongly dependent on the dye : {Mo132} ratio changing the morphology of the oligomers from linear to dense aggregates. © 2023 The Royal Society of Chemistry.
AB - Noncovalent ionic interactions between nanosized Keplerate-type capsules {Mo132} and tetra-cationic porphyrins have been investigated in aqueous solution using small-angle X-ray scattering, 1H NMR and photophysical methods. These complementary multiscale methods reveal the formation of large hybrid oligomers built from a short-range organization in which the cationic porphyrin is glued onto the large POM surface. The local structuring appears to be strongly dependent on the dye : {Mo132} ratio changing the morphology of the oligomers from linear to dense aggregates. © 2023 The Royal Society of Chemistry.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85143967787
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000902043400001
U2 - 10.1039/D2CC05193A
DO - 10.1039/D2CC05193A
M3 - Article
VL - 59
SP - 86
EP - 89
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 1
ER -
ID: 33223880