TY - JOUR

T1 - Effect of the structure of alkylammonium halides on the outcome of carbon dioxide cycloaddition to oxiranes

AU - Gabov, I.

AU - Ezhikova, M. a.

AU - Kodess, M.

AU - Pestov, A.

N1 - The study was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the state assignment for 2023 (subject No. AAAA-A19-119012290116-9). The study was performed using research equipment of the Center for Collective Use “Spectroscopy and Analysis of Organic Compounds”.

PY - 2023/12/1

Y1 - 2023/12/1

N2 - The effect of structure of alkylammonium halides on the outcome of cycloaddition of carbon dioxide to oxiranes was studied. The conversion of epichlorohydrin to chloromethylethylene carbonate depends nonlinearly on the length of the hydrocarbon chain in the alkylammonium halide catalyst. Tetraethylammonium and benzyltriethylammonium were the most effective cations in the catalyst used. Acetone was the solvent of choice for this reaction under the studied conditions.

AB - The effect of structure of alkylammonium halides on the outcome of cycloaddition of carbon dioxide to oxiranes was studied. The conversion of epichlorohydrin to chloromethylethylene carbonate depends nonlinearly on the length of the hydrocarbon chain in the alkylammonium halide catalyst. Tetraethylammonium and benzyltriethylammonium were the most effective cations in the catalyst used. Acetone was the solvent of choice for this reaction under the studied conditions.

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U2 - 10.1007/s11172-023-4089-2

DO - 10.1007/s11172-023-4089-2

M3 - Article

VL - 72

SP - 2809

EP - 2814

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 12

ER -