Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Effect of crystal structure on the electrical properties of CaTi1-xFexO3-δ
AU - Dunyushkina, L.
AU - Gorbunov, V.
PY - 2001/1/1
Y1 - 2001/1/1
N2 - The electrical conductivity of CaTi1-xFexO3-delta (x = 0-0.5) was measured as a function of temperature and oxygen partial pressure. At 1000 degreesC, the highest conductivity was observed at x = 0.2. The crystal structure of the materials with x = 0, 0.2, 0.25, and 0.3 was studied by x-ray powder diffraction and refined by the full-profile analysis method. The results were used to elucidate the mechanisms of the high-temperature (greater than or equal to 1000 degreesC) formation, ordering, and transport of oxygen vacancies in CaTiO3 upon substitution of Fe3+ for Ti4+. The composition dependences of ionic conductivity calculated for CaTi1-xFexO3-delta agree well with experiment.
AB - The electrical conductivity of CaTi1-xFexO3-delta (x = 0-0.5) was measured as a function of temperature and oxygen partial pressure. At 1000 degreesC, the highest conductivity was observed at x = 0.2. The crystal structure of the materials with x = 0, 0.2, 0.25, and 0.3 was studied by x-ray powder diffraction and refined by the full-profile analysis method. The results were used to elucidate the mechanisms of the high-temperature (greater than or equal to 1000 degreesC) formation, ordering, and transport of oxygen vacancies in CaTiO3 upon substitution of Fe3+ for Ti4+. The composition dependences of ionic conductivity calculated for CaTi1-xFexO3-delta agree well with experiment.
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000172328200014
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=9344240452
U2 - 10.1023/A:1012553310827
DO - 10.1023/A:1012553310827
M3 - Article
VL - 37
SP - 1165
EP - 1169
JO - Inorganic Materials
JF - Inorganic Materials
SN - 0020-1685
IS - 11
ER -
ID: 42455444