Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Crystallization kinetics of GdYScAlCo high-entropy bulk metallic glass
AU - Bykov, V. a.
AU - Kovalenko, D. a.
AU - Sterkhov, E. v.
AU - Kulikova, T. v.
N1 - This work was supported by the Russian Science Foundation (grant no. 23-23-00100), https://www.rscf.ru/en.
PY - 2023
Y1 - 2023
N2 - The thermal stability and non-isothermal crystallization of a new bulkamorphous high-entropy (HE-BMG) equiatomic GdYScAlCo alloy were studied by differential scanning calorimetry (DSC). The alloy shows a four-stage crystallization process. The kinetic parameters (activation energy (Eα)), the pre-exponential factor (logA) and glass-forming ability indicators (kinetic fragility index, characteristic temperatures) for the GdYScAlCo alloy were obtained. The Eα values obtained by isoconversional methods indicate a nonlinear Arrhenian behaviour and a complex process. The Avrami equation modification proposed by Jeziorny and the multivariate nonlinear regression method were applied on the nonisothermal crystallization. In the case of primary crystallization of the amorphous GdYScAlCo alloy under nonisothermal conditions, the kinetics of the nucleation process is best described by an autocatalytic reaction.
AB - The thermal stability and non-isothermal crystallization of a new bulkamorphous high-entropy (HE-BMG) equiatomic GdYScAlCo alloy were studied by differential scanning calorimetry (DSC). The alloy shows a four-stage crystallization process. The kinetic parameters (activation energy (Eα)), the pre-exponential factor (logA) and glass-forming ability indicators (kinetic fragility index, characteristic temperatures) for the GdYScAlCo alloy were obtained. The Eα values obtained by isoconversional methods indicate a nonlinear Arrhenian behaviour and a complex process. The Avrami equation modification proposed by Jeziorny and the multivariate nonlinear regression method were applied on the nonisothermal crystallization. In the case of primary crystallization of the amorphous GdYScAlCo alloy under nonisothermal conditions, the kinetics of the nucleation process is best described by an autocatalytic reaction.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85162138200
UR - https://elibrary.ru/item.asp?id=54268149
U2 - 10.15826/chimtech.2023.10.2.07
DO - 10.15826/chimtech.2023.10.2.07
M3 - Article
VL - 10
JO - Chimica Techno Acta
JF - Chimica Techno Acta
SN - 2409-5613
IS - 2
M1 - 202310207
ER -
ID: 41586705