Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Co(II), Cu(II), and Mn(II) complexes based on 2,2’-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species
AU - Moseev, Timofey D.
AU - Nikiforov, Egor A.
AU - Varaksin, Mikhail V.
AU - Valieva, Maria I.
AU - Kopchuk, Dmitry S.
AU - Litvinov, Igor A.
AU - Gaviko, Vasiliy S.
AU - Slepukhin, Pavel A.
AU - Zyryanov, Grigory V.
AU - Charushin, Valery N.
AU - Chupakhin, Oleg N.
N1 - The research was financially supported by the Russian Science Foundation (RSF) according to the research project № 20-73-10077, https://rscf.ru/en/project/20-73-10077/.
PY - 2023/12/1
Y1 - 2023/12/1
N2 - A series of new Co(II), Cu(II), and Mn(II) complexes containing both aromatic and aliphatic organofluorine species were obtained in 76–90% yields. Structural properties of these coordination compounds derived from pentafluorophenyl-substituted 3-(2-pyridyl)-1,2,4-triazine, 2,2′-bipyridine and hexafluoroacetylacetonate ligands were comprehensively studied using by XRD analysis, with the slightly distorted octahedral coordination being revealed in all cases. The spatial characteristics for 3-(2-pyridyl)-1,2,4-triazine bearing pentafluorophenyl moiety at C(5) position as well as its bipyridine analog in relation to ones for the corresponding metal complexes were also studied. The revealed structural features for the elaborated Co(II), Cu(II), and Mn(II) complexes based on 2,2′-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species could be of particular interest in the design of advanced materials for catalysis, chemosensory, molecular electronics, and other fields of materials science.
AB - A series of new Co(II), Cu(II), and Mn(II) complexes containing both aromatic and aliphatic organofluorine species were obtained in 76–90% yields. Structural properties of these coordination compounds derived from pentafluorophenyl-substituted 3-(2-pyridyl)-1,2,4-triazine, 2,2′-bipyridine and hexafluoroacetylacetonate ligands were comprehensively studied using by XRD analysis, with the slightly distorted octahedral coordination being revealed in all cases. The spatial characteristics for 3-(2-pyridyl)-1,2,4-triazine bearing pentafluorophenyl moiety at C(5) position as well as its bipyridine analog in relation to ones for the corresponding metal complexes were also studied. The revealed structural features for the elaborated Co(II), Cu(II), and Mn(II) complexes based on 2,2′-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species could be of particular interest in the design of advanced materials for catalysis, chemosensory, molecular electronics, and other fields of materials science.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85169884488
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001162811100001
U2 - 10.1016/j.ica.2023.121727
DO - 10.1016/j.ica.2023.121727
M3 - Article
VL - 558
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
M1 - 121727
ER -
ID: 44646844