The temperature dependencies of the lattice parameters and magnetization have been studied in the intermetallic compound Tm2Co7. Magnetic ordering is accompanied by spontaneous magnetostriction in the basal plane and along the c axis (2.0 × 10-3 and 2.7 × 10-3 respectively at 5 K). This corresponds to a volume effect ωs = 6.6 × 10-3. The Tm atoms on the quasi-cubic sites are considered to be responsible for the spin reorientation from the uniaxial type of magnetic anisotropy above 45 K to the cone of easy axes below this temperature, which is explained by magnetoelastic effects. In the cone range a large orthorhombic distortion ε{lunate} (up to -3.5 × 10-3 at 5 K) is observed. The additional volume anomaly δωs = -1 × 10-3, which accompanies spin reorientation, can be explained by the anisotropy of the magnetic moments of the thulium and cobalt sublattices.
Original languageEnglish
Pages (from-to)187-190
Number of pages4
JournalJournal of Alloys and Compounds
Volume189
Issue number2
DOIs
Publication statusPublished - 1 Dec 1992

    WoS ResearchAreas Categories

  • Chemistry, Physical
  • Materials Science, Multidisciplinary
  • Metallurgy & Metallurgical Engineering

    ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

ID: 55165170