Standard

Tailoring the linear and nonlinear optical properties of PVC/PE blend polymer by insertion the spindle copper nanoparticles. / Elbasiony, Amr M.; Sharshir, Ahmed Ibrahim; Ghobashy, Mohamed Mohamady et al.
In: Optical Materials, Vol. 148, 114811, 2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Elbasiony, AM, Sharshir, AI, Ghobashy, MM, Alshangiti, DM, Madani, M, Al-Gahtan, SA, Henaish, AMA & Abdelhamied, MM 2024, 'Tailoring the linear and nonlinear optical properties of PVC/PE blend polymer by insertion the spindle copper nanoparticles', Optical Materials, vol. 148, 114811. https://doi.org/10.1016/j.optmat.2023.114811

APA

Elbasiony, A. M., Sharshir, A. I., Ghobashy, M. M., Alshangiti, D. M., Madani, M., Al-Gahtan, S. A., Henaish, A. M. A., & Abdelhamied, M. M. (2024). Tailoring the linear and nonlinear optical properties of PVC/PE blend polymer by insertion the spindle copper nanoparticles. Optical Materials, 148, [114811]. https://doi.org/10.1016/j.optmat.2023.114811

Vancouver

Elbasiony AM, Sharshir AI, Ghobashy MM, Alshangiti DM, Madani M, Al-Gahtan SA et al. Tailoring the linear and nonlinear optical properties of PVC/PE blend polymer by insertion the spindle copper nanoparticles. Optical Materials. 2024;148:114811. doi: 10.1016/j.optmat.2023.114811

Author

Elbasiony, Amr M. ; Sharshir, Ahmed Ibrahim ; Ghobashy, Mohamed Mohamady et al. / Tailoring the linear and nonlinear optical properties of PVC/PE blend polymer by insertion the spindle copper nanoparticles. In: Optical Materials. 2024 ; Vol. 148.

BibTeX

@article{a63317efb8ba46c1b7788ecaf87ad682,
title = "Tailoring the linear and nonlinear optical properties of PVC/PE blend polymer by insertion the spindle copper nanoparticles",
abstract = "PVC/PE polymer nanocomposites were synthesized with 0–3 wt% copper (Cu) nanoparticles via melt extrusion. XRD analysis showed characteristic peaks corresponding to crystalline PVC, PE, and Cu phases. FTIR confirmed the presence of signature vibrational modes of PVC and PE. Optical studies revealed tunable light absorption, refractive index, dielectric response, and bandgap by tailoring copper content. The composites displayed enhanced linear and nonlinear optical susceptibilities, with potential applications in photonics. Optical absorption studies revealed a redshift in bandgap from 3.38 eV to 2.19 eV as Cu concentration increased from 0 to 3%, indicating enhanced visible light absorption. The real dielectric constant rose from 1.3527 to 1.4578 at 190 nm wavelength when Cu content was raised from 0 to 3%. Imaginary dielectric constant exhibited a stepwise enhancement from 2.43 × 10−3 to 3.97 × 10−3 at 190 nm with increasing Cu loading up to 3 %. The nonlinear refractive index varied from 1.2 × 10−8 cm2/W to 2.1 × 10−8 cm2/W across 500–900 nm wavelengths for 0–3% Cu. Meanwhile, the dispersion parameters including, the single oscillator energy (Eo) and the dispersion energy (Ed) were extracted. The relaxation time of the studied samples were extracted, which decreased after the insertion the nanofillers. The outcomes revealed that Cu nanoparticles' doped films favor a high-speed optoelectronic device more than the pristine film. The results demonstrate tunable optical and dielectric characteristics, underscoring the potential of Cu-based PVC/PE nanocomposites.",
author = "Elbasiony, {Amr M.} and Sharshir, {Ahmed Ibrahim} and Ghobashy, {Mohamed Mohamady} and Alshangiti, {Dalal Mohamed} and M. Madani and Al-Gahtan, {Samera Ali} and Henaish, {A. M. A.} and Abdelhamied, {Mostafa M.}",
note = "The authors extend their appreciation to the Deanship of Scientific Research at Northern Border University , Arar, KSA for funding this research work through the project number NBU-FFR-2023-0179.",
year = "2024",
doi = "10.1016/j.optmat.2023.114811",
language = "English",
volume = "148",
journal = "Optical Materials",
issn = "0925-3467",
publisher = "Elsevier BV",

}

RIS

TY - JOUR

T1 - Tailoring the linear and nonlinear optical properties of PVC/PE blend polymer by insertion the spindle copper nanoparticles

AU - Elbasiony, Amr M.

AU - Sharshir, Ahmed Ibrahim

AU - Ghobashy, Mohamed Mohamady

AU - Alshangiti, Dalal Mohamed

AU - Madani, M.

AU - Al-Gahtan, Samera Ali

AU - Henaish, A. M. A.

AU - Abdelhamied, Mostafa M.

N1 - The authors extend their appreciation to the Deanship of Scientific Research at Northern Border University , Arar, KSA for funding this research work through the project number NBU-FFR-2023-0179.

PY - 2024

Y1 - 2024

N2 - PVC/PE polymer nanocomposites were synthesized with 0–3 wt% copper (Cu) nanoparticles via melt extrusion. XRD analysis showed characteristic peaks corresponding to crystalline PVC, PE, and Cu phases. FTIR confirmed the presence of signature vibrational modes of PVC and PE. Optical studies revealed tunable light absorption, refractive index, dielectric response, and bandgap by tailoring copper content. The composites displayed enhanced linear and nonlinear optical susceptibilities, with potential applications in photonics. Optical absorption studies revealed a redshift in bandgap from 3.38 eV to 2.19 eV as Cu concentration increased from 0 to 3%, indicating enhanced visible light absorption. The real dielectric constant rose from 1.3527 to 1.4578 at 190 nm wavelength when Cu content was raised from 0 to 3%. Imaginary dielectric constant exhibited a stepwise enhancement from 2.43 × 10−3 to 3.97 × 10−3 at 190 nm with increasing Cu loading up to 3 %. The nonlinear refractive index varied from 1.2 × 10−8 cm2/W to 2.1 × 10−8 cm2/W across 500–900 nm wavelengths for 0–3% Cu. Meanwhile, the dispersion parameters including, the single oscillator energy (Eo) and the dispersion energy (Ed) were extracted. The relaxation time of the studied samples were extracted, which decreased after the insertion the nanofillers. The outcomes revealed that Cu nanoparticles' doped films favor a high-speed optoelectronic device more than the pristine film. The results demonstrate tunable optical and dielectric characteristics, underscoring the potential of Cu-based PVC/PE nanocomposites.

AB - PVC/PE polymer nanocomposites were synthesized with 0–3 wt% copper (Cu) nanoparticles via melt extrusion. XRD analysis showed characteristic peaks corresponding to crystalline PVC, PE, and Cu phases. FTIR confirmed the presence of signature vibrational modes of PVC and PE. Optical studies revealed tunable light absorption, refractive index, dielectric response, and bandgap by tailoring copper content. The composites displayed enhanced linear and nonlinear optical susceptibilities, with potential applications in photonics. Optical absorption studies revealed a redshift in bandgap from 3.38 eV to 2.19 eV as Cu concentration increased from 0 to 3%, indicating enhanced visible light absorption. The real dielectric constant rose from 1.3527 to 1.4578 at 190 nm wavelength when Cu content was raised from 0 to 3%. Imaginary dielectric constant exhibited a stepwise enhancement from 2.43 × 10−3 to 3.97 × 10−3 at 190 nm with increasing Cu loading up to 3 %. The nonlinear refractive index varied from 1.2 × 10−8 cm2/W to 2.1 × 10−8 cm2/W across 500–900 nm wavelengths for 0–3% Cu. Meanwhile, the dispersion parameters including, the single oscillator energy (Eo) and the dispersion energy (Ed) were extracted. The relaxation time of the studied samples were extracted, which decreased after the insertion the nanofillers. The outcomes revealed that Cu nanoparticles' doped films favor a high-speed optoelectronic device more than the pristine film. The results demonstrate tunable optical and dielectric characteristics, underscoring the potential of Cu-based PVC/PE nanocomposites.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85182025779

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001153823700001

U2 - 10.1016/j.optmat.2023.114811

DO - 10.1016/j.optmat.2023.114811

M3 - Article

VL - 148

JO - Optical Materials

JF - Optical Materials

SN - 0925-3467

M1 - 114811

ER -

ID: 51611630