Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Synthesis of Ultra-High-Molecular-Weight Polyethylene with an Elevated Melting Point in an Octafluorobutane Medium
AU - Rasputin, N. A.
AU - Vlasov, I. A.
AU - Yakovlev, S. V.
AU - Artem’ev, G. A.
AU - Nikonov, I. L.
AU - Kopchuk, D. S.
AU - Matern, A. I.
AU - Charushin, V. N.
PY - 2023/2/1
Y1 - 2023/2/1
N2 - Ultra-high-molecular-weight polyethylene (UHMWPE) with an elevated melting point Tm of up to 144°C has been successfully fabricated by suspension polymerization initiated by Ziegler–Natta catalysts in a 1H,4H-octafluorobutane medium. This method allows one to efficiently perform the polymerization at a near-ambient temperature and a near-atmospheric ethylene pressure. The obtained polyethylenes have been characterized by IR spectroscopy, elemental analysis, and thermal analysis, and the melting points and degrees of crystallinity of the synthesized polymers have been found.
AB - Ultra-high-molecular-weight polyethylene (UHMWPE) with an elevated melting point Tm of up to 144°C has been successfully fabricated by suspension polymerization initiated by Ziegler–Natta catalysts in a 1H,4H-octafluorobutane medium. This method allows one to efficiently perform the polymerization at a near-ambient temperature and a near-atmospheric ethylene pressure. The obtained polyethylenes have been characterized by IR spectroscopy, elemental analysis, and thermal analysis, and the melting points and degrees of crystallinity of the synthesized polymers have been found.
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000993819500002
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85160099538
U2 - 10.1134/S0012500823600141
DO - 10.1134/S0012500823600141
M3 - Article
VL - 508
SP - 56
EP - 61
JO - Doklady Chemistry
JF - Doklady Chemistry
SN - 0012-5008
IS - 2
ER -
ID: 40048961