Standard

Strategy for improving the functional performances of complex oxide through the use of a fluorine-containing precursor. / Osinkin, D.; Zakharov, D.; Khodimchuk, A. et al.
In: International Journal of Hydrogen Energy, Vol. 48, No. 59, 01.07.2023, p. 22624-22633.

Research output: Contribution to journal › Article › peer-review

Harvard

Osinkin, D, Zakharov, D, Khodimchuk, A, Antonova, E, Bogdanovich, N, Gordeev, E, Suntsov, A & Porotnikova, N 2023, 'Strategy for improving the functional performances of complex oxide through the use of a fluorine-containing precursor', International Journal of Hydrogen Energy, vol. 48, no. 59, pp. 22624-22633. https://doi.org/10.1016/j.ijhydene.2023.02.076

APA

Osinkin, D., Zakharov, D., Khodimchuk, A., Antonova, E., Bogdanovich, N., Gordeev, E., Suntsov, A., & Porotnikova, N. (2023). Strategy for improving the functional performances of complex oxide through the use of a fluorine-containing precursor. International Journal of Hydrogen Energy, 48(59), 22624-22633. https://doi.org/10.1016/j.ijhydene.2023.02.076

Vancouver

Osinkin D, Zakharov D, Khodimchuk A, Antonova E, Bogdanovich N, Gordeev E et al. Strategy for improving the functional performances of complex oxide through the use of a fluorine-containing precursor. International Journal of Hydrogen Energy. 2023 Jul 1;48(59):22624-22633. doi: 10.1016/j.ijhydene.2023.02.076

Author

Osinkin, D. ; Zakharov, D. ; Khodimchuk, A. et al. / Strategy for improving the functional performances of complex oxide through the use of a fluorine-containing precursor. In: International Journal of Hydrogen Energy. 2023 ; Vol. 48, No. 59. pp. 22624-22633.

BibTeX

@article{8221a2bb7cf14d5f9b9f4f8fd5e8956d,
title = "Strategy for improving the functional performances of complex oxide through the use of a fluorine-containing precursor",
abstract = "The complex oxide Sr1.95Fe1.4Ni0.1Mo0.5O6-x-5(Fx), where x = 0, 0.1, 0.2 and 0.3, as one of the most promising materials for electrodes of symmetrical electrochemical devices based on solid electrolytes is studied. The unit cell parameter increases monotonically with the addition of the fluorine-containing precursor in the synthesis of materials. The absence of fluorine traces in the sintered oxides was reliably confirmed by a combination of potentiometry using a fluorine-selective electrode and in situ mass spectrometry analysis of the gas media formed during heating the synthesized powders. It is suggested that the use of a fluorine-containing precursor makes it possible to increase the concentration of oxygen vacancies in the oxide, which positively affects its functional characteristics, such as the oxygen exchange rate with the gas phase and the oxygen electroreduction rate.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.",
author = "D. Osinkin and D. Zakharov and A. Khodimchuk and E. Antonova and N. Bogdanovich and E. Gordeev and A. Suntsov and N. Porotnikova",
note = "This work was partly carried out using facilities of the shared access center {\textquoteleft}Composition of Compounds{\textquoteright} IHTE, UB RAS. The authors would like to thank Tamara Kuznetsova for assisting in the study.",
year = "2023",
month = jul,
day = "1",
doi = "10.1016/j.ijhydene.2023.02.076",
language = "English",
volume = "48",
pages = "22624--22633",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier",
number = "59",

}

RIS

TY - JOUR

T1 - Strategy for improving the functional performances of complex oxide through the use of a fluorine-containing precursor

AU - Osinkin, D.

AU - Zakharov, D.

AU - Khodimchuk, A.

AU - Antonova, E.

AU - Bogdanovich, N.

AU - Gordeev, E.

AU - Suntsov, A.

AU - Porotnikova, N.

N1 - This work was partly carried out using facilities of the shared access center ‘Composition of Compounds’ IHTE, UB RAS. The authors would like to thank Tamara Kuznetsova for assisting in the study.

PY - 2023/7/1

Y1 - 2023/7/1

N2 - The complex oxide Sr1.95Fe1.4Ni0.1Mo0.5O6-x-5(Fx), where x = 0, 0.1, 0.2 and 0.3, as one of the most promising materials for electrodes of symmetrical electrochemical devices based on solid electrolytes is studied. The unit cell parameter increases monotonically with the addition of the fluorine-containing precursor in the synthesis of materials. The absence of fluorine traces in the sintered oxides was reliably confirmed by a combination of potentiometry using a fluorine-selective electrode and in situ mass spectrometry analysis of the gas media formed during heating the synthesized powders. It is suggested that the use of a fluorine-containing precursor makes it possible to increase the concentration of oxygen vacancies in the oxide, which positively affects its functional characteristics, such as the oxygen exchange rate with the gas phase and the oxygen electroreduction rate.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

AB - The complex oxide Sr1.95Fe1.4Ni0.1Mo0.5O6-x-5(Fx), where x = 0, 0.1, 0.2 and 0.3, as one of the most promising materials for electrodes of symmetrical electrochemical devices based on solid electrolytes is studied. The unit cell parameter increases monotonically with the addition of the fluorine-containing precursor in the synthesis of materials. The absence of fluorine traces in the sintered oxides was reliably confirmed by a combination of potentiometry using a fluorine-selective electrode and in situ mass spectrometry analysis of the gas media formed during heating the synthesized powders. It is suggested that the use of a fluorine-containing precursor makes it possible to increase the concentration of oxygen vacancies in the oxide, which positively affects its functional characteristics, such as the oxygen exchange rate with the gas phase and the oxygen electroreduction rate.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85149783506

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001035330900001

U2 - 10.1016/j.ijhydene.2023.02.076

DO - 10.1016/j.ijhydene.2023.02.076

M3 - Article

VL - 48

SP - 22624

EP - 22633

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 59

ER -

ID: 40644356