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Sequence of Structural and Magnetic Phase Transitions in (NO)Mn6(NO3)13. / Vorobyova, Anna; Morozov, Igor; Vasilchikova, Tatyana et al.
In: Inorganic Chemistry, Vol. 63, No. 11, 18.03.2024, p. 5199-5207.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorobyova, A, Morozov, I, Vasilchikova, T, Zakharov, K, Ovchenkov, YA, Chistyakov, GD, Ivanova, A, Shvanskaya, L, Lyssenko, K, Pchelkina, Z, Vasiliev, A & Volkova, O 2024, 'Sequence of Structural and Magnetic Phase Transitions in (NO)Mn6(NO3)13', Inorganic Chemistry, vol. 63, no. 11, pp. 5199-5207. https://doi.org/10.1021/acs.inorgchem.4c00180

APA

Vorobyova, A., Morozov, I., Vasilchikova, T., Zakharov, K., Ovchenkov, Y. A., Chistyakov, G. D., Ivanova, A., Shvanskaya, L., Lyssenko, K., Pchelkina, Z., Vasiliev, A., & Volkova, O. (2024). Sequence of Structural and Magnetic Phase Transitions in (NO)Mn6(NO3)13. Inorganic Chemistry, 63(11), 5199-5207. https://doi.org/10.1021/acs.inorgchem.4c00180

Vancouver

Vorobyova A, Morozov I, Vasilchikova T, Zakharov K, Ovchenkov YA, Chistyakov GD et al. Sequence of Structural and Magnetic Phase Transitions in (NO)Mn6(NO3)13. Inorganic Chemistry. 2024 Mar 18;63(11):5199-5207. doi: 10.1021/acs.inorgchem.4c00180

Author

Vorobyova, Anna ; Morozov, Igor ; Vasilchikova, Tatyana et al. / Sequence of Structural and Magnetic Phase Transitions in (NO)Mn6(NO3)13. In: Inorganic Chemistry. 2024 ; Vol. 63, No. 11. pp. 5199-5207.

BibTeX

@article{62c64467b64a4684b7cc50ed6500ab63,
title = "Sequence of Structural and Magnetic Phase Transitions in (NO)Mn6(NO3)13",
abstract = "New nitrosonium manganese(II) nitrate, (NO)Mn6(NO3)13, has been synthesized and structurally characterized. In the temperature range of 45–298 K, the crystal is hexagonal (centrosymmetric sp. gr. P63/m). Mn2+ ions are assembled into tubes along axis c with both NO3– filling and coating. The nitrosonium cation is located in the framework cavity and is disordered by a 3-fold axis. At the temperature TS1 = 190 K, a structural phase transition related to the libration of the intertube NO3 group and a small variation of Mn polyhedron is observed. Moreover, the anomalies in physical properties of (NO)Mn6(NO3)13 allow suggesting that ordering of NO+ units occurs at low temperatures. The antiferromagnetic ordering in this compound is preceded by the formation of a short-range correlation regime at about 25 K and takes place in two steps at TN1 = 12.0 K and TN2 = 8.4 K.",
author = "Anna Vorobyova and Igor Morozov and Tatyana Vasilchikova and Konstantin Zakharov and Ovchenkov, {Yevgeny A.} and Chistyakov, {Gregory D.} and Anna Ivanova and Larisa Shvanskaya and Konstantin Lyssenko and Zlata Pchelkina and Alexander Vasiliev and Olga Volkova",
note = "The research was carried out within the framework of the scientific program of the National Centre of Physics and Mathematics under the project “Research in strong and superstrong magnetic fields”. T.M.V. and L.V.S. acknowledge the support by Megagrant program of Russian Government through project 15-075-2021-604 for synthesis, crystal structure investigation, and ESR measurements. O.S.V. acknowledges the support of RSCF grant 22-42-08002 for measurements of thermodynamic properties. A.A.V. acknowledges support by RSCF grant 22-72-10034. K.A.L. acknowledges support by RSCF grant 22-13-00122 for multitemperature X-ray diffraction investigation. Z.P. acknowledges support by Ministry of Science and Higher Education of the Russian Federation (theme “Quantum” no. 122021000038-7).",
year = "2024",
month = mar,
day = "18",
doi = "10.1021/acs.inorgchem.4c00180",
language = "English",
volume = "63",
pages = "5199--5207",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "11",

}

RIS

TY - JOUR

T1 - Sequence of Structural and Magnetic Phase Transitions in (NO)Mn6(NO3)13

AU - Vorobyova, Anna

AU - Morozov, Igor

AU - Vasilchikova, Tatyana

AU - Zakharov, Konstantin

AU - Ovchenkov, Yevgeny A.

AU - Chistyakov, Gregory D.

AU - Ivanova, Anna

AU - Shvanskaya, Larisa

AU - Lyssenko, Konstantin

AU - Pchelkina, Zlata

AU - Vasiliev, Alexander

AU - Volkova, Olga

N1 - The research was carried out within the framework of the scientific program of the National Centre of Physics and Mathematics under the project “Research in strong and superstrong magnetic fields”. T.M.V. and L.V.S. acknowledge the support by Megagrant program of Russian Government through project 15-075-2021-604 for synthesis, crystal structure investigation, and ESR measurements. O.S.V. acknowledges the support of RSCF grant 22-42-08002 for measurements of thermodynamic properties. A.A.V. acknowledges support by RSCF grant 22-72-10034. K.A.L. acknowledges support by RSCF grant 22-13-00122 for multitemperature X-ray diffraction investigation. Z.P. acknowledges support by Ministry of Science and Higher Education of the Russian Federation (theme “Quantum” no. 122021000038-7).

PY - 2024/3/18

Y1 - 2024/3/18

N2 - New nitrosonium manganese(II) nitrate, (NO)Mn6(NO3)13, has been synthesized and structurally characterized. In the temperature range of 45–298 K, the crystal is hexagonal (centrosymmetric sp. gr. P63/m). Mn2+ ions are assembled into tubes along axis c with both NO3– filling and coating. The nitrosonium cation is located in the framework cavity and is disordered by a 3-fold axis. At the temperature TS1 = 190 K, a structural phase transition related to the libration of the intertube NO3 group and a small variation of Mn polyhedron is observed. Moreover, the anomalies in physical properties of (NO)Mn6(NO3)13 allow suggesting that ordering of NO+ units occurs at low temperatures. The antiferromagnetic ordering in this compound is preceded by the formation of a short-range correlation regime at about 25 K and takes place in two steps at TN1 = 12.0 K and TN2 = 8.4 K.

AB - New nitrosonium manganese(II) nitrate, (NO)Mn6(NO3)13, has been synthesized and structurally characterized. In the temperature range of 45–298 K, the crystal is hexagonal (centrosymmetric sp. gr. P63/m). Mn2+ ions are assembled into tubes along axis c with both NO3– filling and coating. The nitrosonium cation is located in the framework cavity and is disordered by a 3-fold axis. At the temperature TS1 = 190 K, a structural phase transition related to the libration of the intertube NO3 group and a small variation of Mn polyhedron is observed. Moreover, the anomalies in physical properties of (NO)Mn6(NO3)13 allow suggesting that ordering of NO+ units occurs at low temperatures. The antiferromagnetic ordering in this compound is preceded by the formation of a short-range correlation regime at about 25 K and takes place in two steps at TN1 = 12.0 K and TN2 = 8.4 K.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85187106700

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001180782800001

U2 - 10.1021/acs.inorgchem.4c00180

DO - 10.1021/acs.inorgchem.4c00180

M3 - Article

VL - 63

SP - 5199

EP - 5207

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 11

ER -

ID: 55299745