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Schiff Bases Derived from 6-Formyl-3-(4-methoxyphenyl)picolinonitrile: Rational Synthetic Approach and Photophysical Properties. / Kudryashova, E.; Valieva, M.; Shtaitz, Ya. et al.
In: Russian Journal of General Chemistry, Vol. 93, No. S1, 2023, p. S73-S80.

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@article{6d00ee19a5814215b82929d5e54fcd25,
title = "Schiff Bases Derived from 6-Formyl-3-(4-methoxyphenyl)picolinonitrile: Rational Synthetic Approach and Photophysical Properties",
abstract = "A convenient synthetic approach to Schiff bases based on 3-(4-methoxyphenyl)-6-formylpicolinonitrile as surrogates of 2,2′-bipyridine ligands is proposed. The synthesis was carried out using the “1,2,4-triazine” methodology, and a more efficient method for the preparation of 5-aryl-6-cyanopyridine-2-carbaldehydes was developed compared to the previously described one, which involves the use of isonitrosoacetophenone hydrazone and chloroacetonitrile as starting compounds. The resulting compounds exhibit fluorescence in solutions with a quantum yield of up to 15.4%, as well as a fluorescent response to the zinc cation in the form of dramatic fluorescence quenching. {\textcopyright} 2023, Pleiades Publishing, Ltd.",
author = "E. Kudryashova and M. Valieva and Ya. Shtaitz and N. Mochulskaya and A. Krinochkin and D. Kopchuk and G. Zyryanov and V. Rusinov",
note = "The synthesis of Schiff bases and UV study of their complex formation with Zn were performed under financial support of the Grants Council under the President of the Russian Federation (project no. NSh-1223.2022.1.3) and the literature search and photophysical investigations were funded by the Russian Science Foundation (project no. 23-13-00318, https://rscf.ru/project/23-13-00318/ ).",
year = "2023",
doi = "10.1134/S107036322314013X",
language = "English",
volume = "93",
pages = "S73--S80",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "S1",

}

RIS

TY - JOUR

T1 - Schiff Bases Derived from 6-Formyl-3-(4-methoxyphenyl)picolinonitrile: Rational Synthetic Approach and Photophysical Properties

AU - Kudryashova, E.

AU - Valieva, M.

AU - Shtaitz, Ya.

AU - Mochulskaya, N.

AU - Krinochkin, A.

AU - Kopchuk, D.

AU - Zyryanov, G.

AU - Rusinov, V.

N1 - The synthesis of Schiff bases and UV study of their complex formation with Zn were performed under financial support of the Grants Council under the President of the Russian Federation (project no. NSh-1223.2022.1.3) and the literature search and photophysical investigations were funded by the Russian Science Foundation (project no. 23-13-00318, https://rscf.ru/project/23-13-00318/ ).

PY - 2023

Y1 - 2023

N2 - A convenient synthetic approach to Schiff bases based on 3-(4-methoxyphenyl)-6-formylpicolinonitrile as surrogates of 2,2′-bipyridine ligands is proposed. The synthesis was carried out using the “1,2,4-triazine” methodology, and a more efficient method for the preparation of 5-aryl-6-cyanopyridine-2-carbaldehydes was developed compared to the previously described one, which involves the use of isonitrosoacetophenone hydrazone and chloroacetonitrile as starting compounds. The resulting compounds exhibit fluorescence in solutions with a quantum yield of up to 15.4%, as well as a fluorescent response to the zinc cation in the form of dramatic fluorescence quenching. © 2023, Pleiades Publishing, Ltd.

AB - A convenient synthetic approach to Schiff bases based on 3-(4-methoxyphenyl)-6-formylpicolinonitrile as surrogates of 2,2′-bipyridine ligands is proposed. The synthesis was carried out using the “1,2,4-triazine” methodology, and a more efficient method for the preparation of 5-aryl-6-cyanopyridine-2-carbaldehydes was developed compared to the previously described one, which involves the use of isonitrosoacetophenone hydrazone and chloroacetonitrile as starting compounds. The resulting compounds exhibit fluorescence in solutions with a quantum yield of up to 15.4%, as well as a fluorescent response to the zinc cation in the form of dramatic fluorescence quenching. © 2023, Pleiades Publishing, Ltd.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85178931440

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001117621900014

U2 - 10.1134/S107036322314013X

DO - 10.1134/S107036322314013X

M3 - Article

VL - 93

SP - S73-S80

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - S1

ER -

ID: 49825671