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Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles. / Valieva, M. I.; Rammohan, A.; Starnovskaya, E. S. et al.
In: Russian Journal of General Chemistry, Vol. 93, No. 3, 01.03.2023, p. 500-505.

Research output: Contribution to journal › Article › peer-review

Harvard

Valieva, MI, Rammohan, A, Starnovskaya, ES, Kudryashova, EA, Krinochkin, AP, Kopchuk, DS, Zyryanov, GV & Chupakhin, ON 2023, 'Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles', Russian Journal of General Chemistry, vol. 93, no. 3, pp. 500-505. https://doi.org/10.1134/S1070363223030064

APA

Valieva, M. I., Rammohan, A., Starnovskaya, E. S., Kudryashova, E. A., Krinochkin, A. P., Kopchuk, D. S., Zyryanov, G. V., & Chupakhin, O. N. (2023). Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles. Russian Journal of General Chemistry, 93(3), 500-505. https://doi.org/10.1134/S1070363223030064

Vancouver

Valieva MI, Rammohan A, Starnovskaya ES, Kudryashova EA, Krinochkin AP, Kopchuk DS et al. Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles. Russian Journal of General Chemistry. 2023 Mar 1;93(3):500-505. doi: 10.1134/S1070363223030064

Author

Valieva, M. I. ; Rammohan, A. ; Starnovskaya, E. S. et al. / Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles. In: Russian Journal of General Chemistry. 2023 ; Vol. 93, No. 3. pp. 500-505.

BibTeX

@article{06a680b83aea4745855889c1445b4556,
title = "Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles",
abstract = "The reactions of 5-(1,2-dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with various dienophiles (2,5-norbornadiene, 1-morpholinocyclopentene, 1,2-dehydrobenzene, and 2-amino-4-phenyloxazole) were studied. It was shown that the presence of a carborane fragment in the 1,2,4-triazine ring causes an atypical reaction with dienophiles without the formation of the expected aza-Diels–Alder reaction products except for the reaction with 2,5-norbornadiene. The reaction of 5-(1,2-dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with 2-amino-4-phenyloxazole unexpectedly led to the formation of the corresponding 4,5-dihydro-1,2,4-triazines. One of the previously described procedures for the direct introduction of a carborane residue into the C5 position of 1,2,4-triazines was optimized.",
author = "Valieva, {M. I.} and A. Rammohan and Starnovskaya, {E. S.} and Kudryashova, {E. A.} and Krinochkin, {A. P.} and Kopchuk, {D. S.} and Zyryanov, {G. V.} and Chupakhin, {O. N.}",
note = "This work was financially supported by the Council for Grants under the President of the Russian Federation (grant no. MK-320.2021.1.3).",
year = "2023",
month = mar,
day = "1",
doi = "10.1134/S1070363223030064",
language = "English",
volume = "93",
pages = "500--505",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "3",

}

RIS

TY - JOUR

T1 - Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles

AU - Valieva, M. I.

AU - Rammohan, A.

AU - Starnovskaya, E. S.

AU - Kudryashova, E. A.

AU - Krinochkin, A. P.

AU - Kopchuk, D. S.

AU - Zyryanov, G. V.

AU - Chupakhin, O. N.

N1 - This work was financially supported by the Council for Grants under the President of the Russian Federation (grant no. MK-320.2021.1.3).

PY - 2023/3/1

Y1 - 2023/3/1

N2 - The reactions of 5-(1,2-dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with various dienophiles (2,5-norbornadiene, 1-morpholinocyclopentene, 1,2-dehydrobenzene, and 2-amino-4-phenyloxazole) were studied. It was shown that the presence of a carborane fragment in the 1,2,4-triazine ring causes an atypical reaction with dienophiles without the formation of the expected aza-Diels–Alder reaction products except for the reaction with 2,5-norbornadiene. The reaction of 5-(1,2-dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with 2-amino-4-phenyloxazole unexpectedly led to the formation of the corresponding 4,5-dihydro-1,2,4-triazines. One of the previously described procedures for the direct introduction of a carborane residue into the C5 position of 1,2,4-triazines was optimized.

AB - The reactions of 5-(1,2-dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with various dienophiles (2,5-norbornadiene, 1-morpholinocyclopentene, 1,2-dehydrobenzene, and 2-amino-4-phenyloxazole) were studied. It was shown that the presence of a carborane fragment in the 1,2,4-triazine ring causes an atypical reaction with dienophiles without the formation of the expected aza-Diels–Alder reaction products except for the reaction with 2,5-norbornadiene. The reaction of 5-(1,2-dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with 2-amino-4-phenyloxazole unexpectedly led to the formation of the corresponding 4,5-dihydro-1,2,4-triazines. One of the previously described procedures for the direct introduction of a carborane residue into the C5 position of 1,2,4-triazines was optimized.

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UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000978371800006

U2 - 10.1134/S1070363223030064

DO - 10.1134/S1070363223030064

M3 - Article

VL - 93

SP - 500

EP - 505

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 3

ER -

ID: 38533357