Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Preparation and structure of chitosan-silica organic-inorganic hybrid films
AU - Tyukova, I. S.
AU - Suvorova, A. I.
AU - Okuneva, A. I.
AU - Shishkin, E. I.
N1 - This work was supported by the Russian Foundation for Basic Research (project no. 08 03 00552).
PY - 2010/10/1
Y1 - 2010/10/1
N2 - Organic-inorganic hybrid films are prepared via the hydrolysis and polycondensation of tetraethoxysilane in chitosan solutions. It is shown that the composition of reagents, the time of synthesis, the crosslinking of chitosan macromolecules via amino groups by glutaric aldehyde, and the conditions of drying affect structurization of the resulting films. With the use of optical polarization microscopy and atomic force microscopy, it is found that the films contain silica particles with a wide size distribution. The crosslinking of the chitosan matrix by glutaric aldehyde results in the predominant formation of inorganic nanoparticles in the films. A good sorption capacity of the films for copper ions in solutions is found. It increases by a factor of 1.7 as the content of the silica in the films increases to 30 wt %.
AB - Organic-inorganic hybrid films are prepared via the hydrolysis and polycondensation of tetraethoxysilane in chitosan solutions. It is shown that the composition of reagents, the time of synthesis, the crosslinking of chitosan macromolecules via amino groups by glutaric aldehyde, and the conditions of drying affect structurization of the resulting films. With the use of optical polarization microscopy and atomic force microscopy, it is found that the films contain silica particles with a wide size distribution. The crosslinking of the chitosan matrix by glutaric aldehyde results in the predominant formation of inorganic nanoparticles in the films. A good sorption capacity of the films for copper ions in solutions is found. It increases by a factor of 1.7 as the content of the silica in the films increases to 30 wt %.
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000286006100007
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=78149430445
U2 - 10.1134/S1560090410090071
DO - 10.1134/S1560090410090071
M3 - Article
VL - 52
SP - 564
EP - 570
JO - Polymer Science - Series B
JF - Polymer Science - Series B
SN - 1560-0904
IS - 9-10
ER -
ID: 37886720