Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Potentiometric Sensor Based on Layered Pillar[6]arene—Copper Composite
AU - Sorvin, Michail
AU - Galimzyanova, Guzeliya
AU - Evtugyn, Vladimir
AU - Ivanov, Alexey
AU - Shurpik, Dmitry
AU - Stoikov, Ivan
AU - Evtugyn, Gennady
N1 - This research was funded by the Russian Science Foundation, grant number 22-13-00070.
PY - 2023
Y1 - 2023
N2 - A solid-contact potentiometric sensor has been developed on the basis of glassy carbon electrode covered with electropolymerized polyaniline and alternatively layered pillar[6]arene and Cu2+ ions films. The assembly of the surface layer was confirmed by surface plasmon resonance measurements. The number of deposited layers was selected to reach better analytical characteristics for Cu2+ determination. It was shown that better results were achieved by using five layers, the upper one consisting of the macrocycle. The addition of covering layers for polyelectrolytes (Nafion, poly(styrene sulfonate)) and Cu2+ ions did not improve sensor performance. The potentiometric sensor made it possible to determine Cu2+ ions in neutral and weakly acidic media with a linear range of the concentrations, from 3.0 mu M to 10.0 mM (limit of detection 3.0 mu M). The applicability of the sensor in real sample assays was confirmed by the determination of Cu2+ ions in copper vitriol, Bordeaux mixture, and polyvitamin-mineral pills of "Complivit" during an atomic emission spectroscopy analysis.
AB - A solid-contact potentiometric sensor has been developed on the basis of glassy carbon electrode covered with electropolymerized polyaniline and alternatively layered pillar[6]arene and Cu2+ ions films. The assembly of the surface layer was confirmed by surface plasmon resonance measurements. The number of deposited layers was selected to reach better analytical characteristics for Cu2+ determination. It was shown that better results were achieved by using five layers, the upper one consisting of the macrocycle. The addition of covering layers for polyelectrolytes (Nafion, poly(styrene sulfonate)) and Cu2+ ions did not improve sensor performance. The potentiometric sensor made it possible to determine Cu2+ ions in neutral and weakly acidic media with a linear range of the concentrations, from 3.0 mu M to 10.0 mM (limit of detection 3.0 mu M). The applicability of the sensor in real sample assays was confirmed by the determination of Cu2+ ions in copper vitriol, Bordeaux mixture, and polyvitamin-mineral pills of "Complivit" during an atomic emission spectroscopy analysis.
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000914462500001
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85146805101
U2 - 10.3390/chemosensors11010012
DO - 10.3390/chemosensors11010012
M3 - Article
VL - 11
JO - Chemosensors
JF - Chemosensors
SN - 2227-9040
IS - 1
M1 - 12
ER -
ID: 33973195