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Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior. / Smirnova, Kristina A.; Edilova , Yulia O.; Kiskin, Mikhail A. et al.
In: International Journal of Molecular Sciences, Vol. 24, No. 11, 9778, 2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Smirnova, KA, Edilova , YO, Kiskin, MA, Bogomyakov, AS, Kudyakova, YS, Valova , MS, Romanenko, GV, Slepukhin, PA, Saloutin, VI & Bazhin, DN 2023, 'Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior', International Journal of Molecular Sciences, vol. 24, no. 11, 9778. https://doi.org/10.3390/ijms24119778

APA

Smirnova, K. A., Edilova , Y. O., Kiskin, M. A., Bogomyakov, A. S., Kudyakova, Y. S., Valova , M. S., Romanenko, G. V., Slepukhin, P. A., Saloutin, V. I., & Bazhin, D. N. (2023). Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior. International Journal of Molecular Sciences, 24(11), [9778]. https://doi.org/10.3390/ijms24119778

Vancouver

Smirnova KA, Edilova YO, Kiskin MA, Bogomyakov AS, Kudyakova YS, Valova MS et al. Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior. International Journal of Molecular Sciences. 2023;24(11):9778. doi: 10.3390/ijms24119778

Author

Smirnova, Kristina A. ; Edilova , Yulia O. ; Kiskin, Mikhail A. et al. / Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior. In: International Journal of Molecular Sciences. 2023 ; Vol. 24, No. 11.

BibTeX

@article{00db9303ca67439c85441cdcf329b668,
title = "Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior",
abstract = "Functionalized perfluoroalkyl lithium β-diketonates (LiL) react with lanthanide(III) salts (Ln = Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula [(LnL3)(LiL)(MeOH)]. The length of fluoroalkyl substituent in ligand was found to affect the crystal packing of complexes. Photoluminescent and magnetic properties of heterobimetallic β-diketonates in the solid state are reported. The effect of the geometry of the [LnO8] coordination environment of heterometallic β-diketonates on the luminescent properties (quantum yields, phosphorescence lifetimes for Eu, Tb, Dy complexes) and single-ion magnet behavior (Ueff for Dy complexes) is revealed. {\textcopyright} 2023 by the authors.",
author = "Smirnova, {Kristina A.} and Edilova, {Yulia O.} and Kiskin, {Mikhail A.} and Bogomyakov, {Artem S.} and Kudyakova, {Yulia S.} and Valova, {Marina S.} and Romanenko, {Galina V.} and Slepukhin, {Pavel A.} and Saloutin, {Victor I.} and Bazhin, {Denis N.}",
note = "This work carried out in the framework of the basic theme of the Russian Academy of Sciences (state registration № AAAA-A19-119011790132-7).",
year = "2023",
doi = "10.3390/ijms24119778",
language = "English",
volume = "24",
journal = "International Journal of Molecular Sciences",
issn = "1661-6596",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "11",

}

RIS

TY - JOUR

T1 - Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior

AU - Smirnova, Kristina A.

AU - Edilova , Yulia O.

AU - Kiskin, Mikhail A.

AU - Bogomyakov, Artem S.

AU - Kudyakova, Yulia S.

AU - Valova , Marina S.

AU - Romanenko, Galina V.

AU - Slepukhin, Pavel A.

AU - Saloutin, Victor I.

AU - Bazhin, Denis N.

N1 - This work carried out in the framework of the basic theme of the Russian Academy of Sciences (state registration № AAAA-A19-119011790132-7).

PY - 2023

Y1 - 2023

N2 - Functionalized perfluoroalkyl lithium β-diketonates (LiL) react with lanthanide(III) salts (Ln = Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula [(LnL3)(LiL)(MeOH)]. The length of fluoroalkyl substituent in ligand was found to affect the crystal packing of complexes. Photoluminescent and magnetic properties of heterobimetallic β-diketonates in the solid state are reported. The effect of the geometry of the [LnO8] coordination environment of heterometallic β-diketonates on the luminescent properties (quantum yields, phosphorescence lifetimes for Eu, Tb, Dy complexes) and single-ion magnet behavior (Ueff for Dy complexes) is revealed. © 2023 by the authors.

AB - Functionalized perfluoroalkyl lithium β-diketonates (LiL) react with lanthanide(III) salts (Ln = Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula [(LnL3)(LiL)(MeOH)]. The length of fluoroalkyl substituent in ligand was found to affect the crystal packing of complexes. Photoluminescent and magnetic properties of heterobimetallic β-diketonates in the solid state are reported. The effect of the geometry of the [LnO8] coordination environment of heterometallic β-diketonates on the luminescent properties (quantum yields, phosphorescence lifetimes for Eu, Tb, Dy complexes) and single-ion magnet behavior (Ueff for Dy complexes) is revealed. © 2023 by the authors.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85161879357

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001006406500001

U2 - 10.3390/ijms24119778

DO - 10.3390/ijms24119778

M3 - Article

VL - 24

JO - International Journal of Molecular Sciences

JF - International Journal of Molecular Sciences

SN - 1661-6596

IS - 11

M1 - 9778

ER -

ID: 40601608