Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - New 3-aryl(hetaryl)-1-(benzo[d]thiazol-2-yl)-6-methyl-5-phenylverdazyls: the synthesis and spectral and electrochemical properties
AU - Fedorchenko, T.
AU - Lipunova, G.
AU - Shchepochkin, A.
AU - Averkov, M.
AU - Tsmokalyuk, A.
AU - Tungusov, V.
AU - Slepukhin, P.
AU - Chupakhin, O.
N1 - This work was carried out using the equipment of the “Spectroscopy and Analysis of Organic Compounds” Center for Joint Use at the I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences.
PY - 2023/12/1
Y1 - 2023/12/1
N2 - New 3-aryl(hetaryl)-1-(benzo[d]thiazol-2-yl)-6-methyl-5-phenylverdazyls were synthesized and characterized by EPR and IR spectroscopies, mass spectrometry, cyclic voltammetry, and X-ray diffraction. The effect of substituents on the spectral and electrochemical properties was studied. It was shown that substituents at position 3 of the verdazyl tetrazine ring, regardless of their nature, cause a significant shift of the oxidation and reduction potentials to the anodic region. The results obtained suggest that the synthesized compounds can be used as an electroactive components in rechargeable organic batteries.
AB - New 3-aryl(hetaryl)-1-(benzo[d]thiazol-2-yl)-6-methyl-5-phenylverdazyls were synthesized and characterized by EPR and IR spectroscopies, mass spectrometry, cyclic voltammetry, and X-ray diffraction. The effect of substituents on the spectral and electrochemical properties was studied. It was shown that substituents at position 3 of the verdazyl tetrazine ring, regardless of their nature, cause a significant shift of the oxidation and reduction potentials to the anodic region. The results obtained suggest that the synthesized compounds can be used as an electroactive components in rechargeable organic batteries.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85183663568
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001154671000007
U2 - 10.1007/s11172-023-4096-3
DO - 10.1007/s11172-023-4096-3
M3 - Article
VL - 72
SP - 2867
EP - 2877
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 12
ER -
ID: 52302210