Model Describing of the Loose Zinc Electrodeposition Process in the Pulse-Potential Modes

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Model Describing of the Loose Zinc Electrodeposition Process in the Pulse-Potential Modes. / Nikitin, V.; Ostanina, T.; Rudoy, V.
In: Russian Journal of Electrochemistry, Vol. 60, No. 2, 2024, p. 116-128.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{ae423fd5f650437c8e126395187b1503,

title = "Model Describing of the Loose Zinc Electrodeposition Process in the Pulse-Potential Modes",

abstract = "The structural characteristics of loose zinc deposits obtained in pulse-potential modes are calculated using a phenomenological model. Increasing the duty cycle leads to intensified anodic dissolution during pauses and obtaining of denser deposits, due to the formation of dendrites with fewer tips, yet, a larger diameter as compared to the deposits obtained in the potentiostatic mode. The linear dependence of the diameter of the tips of dendrites forming a loose zinc deposit on the duty cycle is found. There is a critical time corresponding to the achievement of zero deposit growth rate when the metal deposited during the pulse will completely dissolve during the pause. {\textcopyright} Pleiades Publishing, Ltd. 2024. ISSN 1023-1935, Russian Journal of Electrochemistry, 2024, Vol. 60, No. 2, pp. 116–128. Pleiades Publishing, Ltd., 2024.",

author = "V. Nikitin and T. Ostanina and V. Rudoy",

note = "The research funding from the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program) is gratefully acknowledged.",

year = "2024",

doi = "10.1134/S1023193524020034",

language = "English",

volume = "60",

pages = "116--128",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "Pleiades Publishing",

number = "2",

}

RIS

TY - JOUR

T1 - Model Describing of the Loose Zinc Electrodeposition Process in the Pulse-Potential Modes

AU - Nikitin, V.

AU - Ostanina, T.

AU - Rudoy, V.

N1 - The research funding from the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program) is gratefully acknowledged.

PY - 2024

Y1 - 2024

N2 - The structural characteristics of loose zinc deposits obtained in pulse-potential modes are calculated using a phenomenological model. Increasing the duty cycle leads to intensified anodic dissolution during pauses and obtaining of denser deposits, due to the formation of dendrites with fewer tips, yet, a larger diameter as compared to the deposits obtained in the potentiostatic mode. The linear dependence of the diameter of the tips of dendrites forming a loose zinc deposit on the duty cycle is found. There is a critical time corresponding to the achievement of zero deposit growth rate when the metal deposited during the pulse will completely dissolve during the pause. © Pleiades Publishing, Ltd. 2024. ISSN 1023-1935, Russian Journal of Electrochemistry, 2024, Vol. 60, No. 2, pp. 116–128. Pleiades Publishing, Ltd., 2024.

AB - The structural characteristics of loose zinc deposits obtained in pulse-potential modes are calculated using a phenomenological model. Increasing the duty cycle leads to intensified anodic dissolution during pauses and obtaining of denser deposits, due to the formation of dendrites with fewer tips, yet, a larger diameter as compared to the deposits obtained in the potentiostatic mode. The linear dependence of the diameter of the tips of dendrites forming a loose zinc deposit on the duty cycle is found. There is a critical time corresponding to the achievement of zero deposit growth rate when the metal deposited during the pulse will completely dissolve during the pause. © Pleiades Publishing, Ltd. 2024. ISSN 1023-1935, Russian Journal of Electrochemistry, 2024, Vol. 60, No. 2, pp. 116–128. Pleiades Publishing, Ltd., 2024.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85191653182

U2 - 10.1134/S1023193524020034

DO - 10.1134/S1023193524020034

M3 - Article

VL - 60

SP - 116

EP - 128

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 2

ER -

ID: 56639997