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Mechanosynthesis of Diaminobiphenyls-Based Schiff’s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion. / Al-Ithawi, Wahab k. a.; Khasanov, Albert f.; Kovalev, Igor s. et al.
In: Chemistry (Switzerland), Vol. 5, No. 2, 2023, p. 978-986.

Research output: Contribution to journal › Article › peer-review

Harvard

Al-Ithawi, WKA, Khasanov, AF, Kovalev, IS, Nikonov, IL, Kopchuk, DS, Platonov, VA, Santra, S, Zyryanov, GV & Ranu, BC 2023, 'Mechanosynthesis of Diaminobiphenyls-Based Schiff’s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion', Chemistry (Switzerland), vol. 5, no. 2, pp. 978-986. https://doi.org/10.3390/chemistry5020066

APA

Al-Ithawi, W. K. A., Khasanov, A. F., Kovalev, I. S., Nikonov, I. L., Kopchuk, D. S., Platonov, V. A., Santra, S., Zyryanov, G. V., & Ranu, B. C. (2023). Mechanosynthesis of Diaminobiphenyls-Based Schiff’s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion. Chemistry (Switzerland), 5(2), 978-986. https://doi.org/10.3390/chemistry5020066

Vancouver

Al-Ithawi WKA, Khasanov AF, Kovalev IS, Nikonov IL, Kopchuk DS, Platonov VA et al. Mechanosynthesis of Diaminobiphenyls-Based Schiff’s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion. Chemistry (Switzerland). 2023;5(2):978-986. doi: 10.3390/chemistry5020066

Author

Al-Ithawi, Wahab k. a. ; Khasanov, Albert f. ; Kovalev, Igor s. et al. / Mechanosynthesis of Diaminobiphenyls-Based Schiff’s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion. In: Chemistry (Switzerland). 2023 ; Vol. 5, No. 2. pp. 978-986.

BibTeX

@article{403e4a61e1e54dc0848cce230d6a701d,
title = "Mechanosynthesis of Diaminobiphenyls-Based Schiff{\textquoteright}s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion",
abstract = "Cyanide ions are known to be lethal for insects and mammals and harmful for the environment, and new methods for their selective detection are in high demand. Herein, the mechanosynthesis of simple Schiff{\textquoteright}s bases-based probes S1–S3 for visual detection of CN− anion is reported. These probes were obtained by means of a reaction between isomeric 4,4-, 3,3- and 2,2-diaminobiphenyls and 4-nitrobenzaldehyde under ball milling conditions. The probes showed high selectivity and sensitivity toward CN− anion via a dramatic “yellow-to-dark purple” color change with a detection limit of 26 × 103, 8.7 × 103 and 14 × 103 ppm for S1–S3, respectively. The proposed mechanism of the detection suggests the deprotonation of a proton from an imine moiety, followed by the formation of charge transfer complexes (CTC).",
author = "Al-Ithawi, {Wahab k. a.} and Khasanov, {Albert f.} and Kovalev, {Igor s.} and Nikonov, {Igor l.} and Kopchuk, {Dmitry s.} and Platonov, {Vadim a.} and Sougata Santra and Zyryanov, {Grigory v.} and Ranu, {Brindaban c.}",
note = "This research was funded by the Ministry of Science and Higher Education of the Russian Federation (Agreement # 075-15-2022-1118 accessed on 29 June 2022).",
year = "2023",
doi = "10.3390/chemistry5020066",
language = "English",
volume = "5",
pages = "978--986",
journal = "Chemistry (Switzerland)",
issn = "2624-8549",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "2",

}

RIS

TY - JOUR

T1 - Mechanosynthesis of Diaminobiphenyls-Based Schiff’s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion

AU - Al-Ithawi, Wahab k. a.

AU - Khasanov, Albert f.

AU - Kovalev, Igor s.

AU - Nikonov, Igor l.

AU - Kopchuk, Dmitry s.

AU - Platonov, Vadim a.

AU - Santra, Sougata

AU - Zyryanov, Grigory v.

AU - Ranu, Brindaban c.

N1 - This research was funded by the Ministry of Science and Higher Education of the Russian Federation (Agreement # 075-15-2022-1118 accessed on 29 June 2022).

PY - 2023

Y1 - 2023

N2 - Cyanide ions are known to be lethal for insects and mammals and harmful for the environment, and new methods for their selective detection are in high demand. Herein, the mechanosynthesis of simple Schiff’s bases-based probes S1–S3 for visual detection of CN− anion is reported. These probes were obtained by means of a reaction between isomeric 4,4-, 3,3- and 2,2-diaminobiphenyls and 4-nitrobenzaldehyde under ball milling conditions. The probes showed high selectivity and sensitivity toward CN− anion via a dramatic “yellow-to-dark purple” color change with a detection limit of 26 × 103, 8.7 × 103 and 14 × 103 ppm for S1–S3, respectively. The proposed mechanism of the detection suggests the deprotonation of a proton from an imine moiety, followed by the formation of charge transfer complexes (CTC).

AB - Cyanide ions are known to be lethal for insects and mammals and harmful for the environment, and new methods for their selective detection are in high demand. Herein, the mechanosynthesis of simple Schiff’s bases-based probes S1–S3 for visual detection of CN− anion is reported. These probes were obtained by means of a reaction between isomeric 4,4-, 3,3- and 2,2-diaminobiphenyls and 4-nitrobenzaldehyde under ball milling conditions. The probes showed high selectivity and sensitivity toward CN− anion via a dramatic “yellow-to-dark purple” color change with a detection limit of 26 × 103, 8.7 × 103 and 14 × 103 ppm for S1–S3, respectively. The proposed mechanism of the detection suggests the deprotonation of a proton from an imine moiety, followed by the formation of charge transfer complexes (CTC).

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85163654667

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001014173000001

U2 - 10.3390/chemistry5020066

DO - 10.3390/chemistry5020066

M3 - Article

VL - 5

SP - 978

EP - 986

JO - Chemistry (Switzerland)

JF - Chemistry (Switzerland)

SN - 2624-8549

IS - 2

ER -

ID: 41541854