Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O

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Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O. / Taran, L. S.; Elfimova, V. Y.; Streltsov, S. V.
In: JETP Letters, Vol. 117, No. 8, 01.04.2023, p. 606-611.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{8e24760a89c14d30a613baedfa19bfd3,

title = "Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O",

abstract = "Studying of single-molecule magnets has sprung many surprises such as, e.g., quantum tunneling of the magnetization, which is strongly related to the presence of a magnetic anisotropy. Electron spin resonance and inelastic neutron scattering measurements of (PPh4)2[ReF6]⋅2H2O complex evidence an unprecedented large single-site magnetic anisotropy of D∼35 K in this material. Using state-of-the-art ab initio calculations we found that the single-ion anisotropy is indeed very large (but does not exceed 12 K) and revealed the physical mechanism lying behind this phenomenon.",

author = "Taran, {L. S.} and Elfimova, {V. Y.} and Streltsov, {S. V.}",

note = "We are grateful to Prof. A. Rogalev for drawing our attention to this Re SIM and E. Komleva for a detailed discussion of the paper. Computations were performed on the Uran supercomputer at the Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences.",

year = "2023",

month = apr,

day = "1",

doi = "10.1134/S0021364023600623",

language = "English",

volume = "117",

pages = "606--611",

journal = "JETP Letters",

issn = "0021-3640",

publisher = "Pleiades Publishing",

number = "8",

}

RIS

TY - JOUR

T1 - Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O

AU - Taran, L. S.

AU - Elfimova, V. Y.

AU - Streltsov, S. V.

N1 - We are grateful to Prof. A. Rogalev for drawing our attention to this Re SIM and E. Komleva for a detailed discussion of the paper. Computations were performed on the Uran supercomputer at the Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences.

PY - 2023/4/1

Y1 - 2023/4/1

N2 - Studying of single-molecule magnets has sprung many surprises such as, e.g., quantum tunneling of the magnetization, which is strongly related to the presence of a magnetic anisotropy. Electron spin resonance and inelastic neutron scattering measurements of (PPh4)2[ReF6]⋅2H2O complex evidence an unprecedented large single-site magnetic anisotropy of D∼35 K in this material. Using state-of-the-art ab initio calculations we found that the single-ion anisotropy is indeed very large (but does not exceed 12 K) and revealed the physical mechanism lying behind this phenomenon.

AB - Studying of single-molecule magnets has sprung many surprises such as, e.g., quantum tunneling of the magnetization, which is strongly related to the presence of a magnetic anisotropy. Electron spin resonance and inelastic neutron scattering measurements of (PPh4)2[ReF6]⋅2H2O complex evidence an unprecedented large single-site magnetic anisotropy of D∼35 K in this material. Using state-of-the-art ab initio calculations we found that the single-ion anisotropy is indeed very large (but does not exceed 12 K) and revealed the physical mechanism lying behind this phenomenon.

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000966673800005

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85152675002

U2 - 10.1134/S0021364023600623

DO - 10.1134/S0021364023600623

M3 - Article

VL - 117

SP - 606

EP - 611

JO - JETP Letters

JF - JETP Letters

SN - 0021-3640

IS - 8

ER -

ID: 40051155