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Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH. / Samarin, Aleksandr Sh.; Trussov, Ivan A.; Pchelkina, Zlata et al.
In: Angewandte Chemie - International Edition, Vol. 63, No. 3, e202316719, 15.01.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Samarin, AS, Trussov, IA, Pchelkina, Z, Fedotov, SS, Ovchenkov, YA, Zhurenko, S, Tkachev, A, Gippius, A, Shvanskaya, L & Vasiliev, AN 2024, 'Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH', Angewandte Chemie - International Edition, vol. 63, no. 3, e202316719. https://doi.org/10.1002/anie.202316719, https://doi.org/10.1002/anie.v63.3

APA

Samarin, A. S., Trussov, I. A., Pchelkina, Z., Fedotov, S. S., Ovchenkov, Y. A., Zhurenko, S., Tkachev, A., Gippius, A., Shvanskaya, L., & Vasiliev, A. N. (2024). Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH. Angewandte Chemie - International Edition, 63(3), [e202316719]. https://doi.org/10.1002/anie.202316719, https://doi.org/10.1002/anie.v63.3

Vancouver

Samarin AS, Trussov IA, Pchelkina Z, Fedotov SS, Ovchenkov YA, Zhurenko S et al. Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH. Angewandte Chemie - International Edition. 2024 Jan 15;63(3):e202316719. doi: 10.1002/anie.202316719, 10.1002/anie.v63.3

Author

Samarin, Aleksandr Sh. ; Trussov, Ivan A. ; Pchelkina, Zlata et al. / Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH. In: Angewandte Chemie - International Edition. 2024 ; Vol. 63, No. 3.

BibTeX

@article{8fba51af182a4009812b7a5f649bd939,
title = "Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH",
abstract = "A novel vanadium hydroxide-phosphate, NH4VPO4OH, was synthesized hydrothermally in V2O5−NH4H2PO4-citric acid system at 230 °C. It was characterized by XRD, TG-DSC, SEM-EDX, FTIR and NMR spectroscopy. NH4VPO4OH is isostructural with NH4GaPO4OH and features edge-sharing chains of VO6 octahedra. These chains running along [010] direction of the unit cell are connected by phosphate tetrahedra to form infinite layers parallel to the (100) plane. Ammonium cations are embedded between the heteropolyhedral layers. According to the thermodynamic and NMR measurements supported by the first-principles calculations, NH4VPO4OH presents a rare case of Haldane spin system with spin S=1 based on V3+ ions. {\textcopyright} 2023 Wiley-VCH GmbH.",
author = "Samarin, {Aleksandr Sh.} and Trussov, {Ivan A.} and Zlata Pchelkina and Fedotov, {Stanislav S.} and Ovchenkov, {Yevgeniy A.} and Sergei Zhurenko and Alexei Tkachev and Andrei Gippius and Larisa Shvanskaya and Vasiliev, {Alexander N.}",
note = "LVS and ANV acknowledge support by Megagrant program of the Government of Russian Federation through the project 15-075-2021-604 for the thermodynamic investigation. AShS, IAT and SSF appreciate support by Russian Science Foundation (Grant 23-73-10125) for the design, synthesis and material characterization. The research was carried out within the framework of the scientific program of the National Centre of Physics and Mathematics under the project “Research in strong and superstrong magnetic fields”. PZV thanks for support the Ministry of Science and Higher Education of the Russian Federation (theme “Spin” No. 122021000036-3). The authors are grateful to Dr. A. Volkov for fruitful discussions and to AICF at Skoltech for providing access to electron microscopy equipment.",
year = "2024",
month = jan,
day = "15",
doi = "10.1002/anie.202316719",
language = "English",
volume = "63",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "Wiley-VCH Verlag",
number = "3",

}

RIS

TY - JOUR

T1 - Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH

AU - Samarin, Aleksandr Sh.

AU - Trussov, Ivan A.

AU - Pchelkina, Zlata

AU - Fedotov, Stanislav S.

AU - Ovchenkov, Yevgeniy A.

AU - Zhurenko, Sergei

AU - Tkachev, Alexei

AU - Gippius, Andrei

AU - Shvanskaya, Larisa

AU - Vasiliev, Alexander N.

N1 - LVS and ANV acknowledge support by Megagrant program of the Government of Russian Federation through the project 15-075-2021-604 for the thermodynamic investigation. AShS, IAT and SSF appreciate support by Russian Science Foundation (Grant 23-73-10125) for the design, synthesis and material characterization. The research was carried out within the framework of the scientific program of the National Centre of Physics and Mathematics under the project “Research in strong and superstrong magnetic fields”. PZV thanks for support the Ministry of Science and Higher Education of the Russian Federation (theme “Spin” No. 122021000036-3). The authors are grateful to Dr. A. Volkov for fruitful discussions and to AICF at Skoltech for providing access to electron microscopy equipment.

PY - 2024/1/15

Y1 - 2024/1/15

N2 - A novel vanadium hydroxide-phosphate, NH4VPO4OH, was synthesized hydrothermally in V2O5−NH4H2PO4-citric acid system at 230 °C. It was characterized by XRD, TG-DSC, SEM-EDX, FTIR and NMR spectroscopy. NH4VPO4OH is isostructural with NH4GaPO4OH and features edge-sharing chains of VO6 octahedra. These chains running along [010] direction of the unit cell are connected by phosphate tetrahedra to form infinite layers parallel to the (100) plane. Ammonium cations are embedded between the heteropolyhedral layers. According to the thermodynamic and NMR measurements supported by the first-principles calculations, NH4VPO4OH presents a rare case of Haldane spin system with spin S=1 based on V3+ ions. © 2023 Wiley-VCH GmbH.

AB - A novel vanadium hydroxide-phosphate, NH4VPO4OH, was synthesized hydrothermally in V2O5−NH4H2PO4-citric acid system at 230 °C. It was characterized by XRD, TG-DSC, SEM-EDX, FTIR and NMR spectroscopy. NH4VPO4OH is isostructural with NH4GaPO4OH and features edge-sharing chains of VO6 octahedra. These chains running along [010] direction of the unit cell are connected by phosphate tetrahedra to form infinite layers parallel to the (100) plane. Ammonium cations are embedded between the heteropolyhedral layers. According to the thermodynamic and NMR measurements supported by the first-principles calculations, NH4VPO4OH presents a rare case of Haldane spin system with spin S=1 based on V3+ ions. © 2023 Wiley-VCH GmbH.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85179750397

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001126400600001

U2 - 10.1002/anie.202316719

DO - 10.1002/anie.202316719

M3 - Article

VL - 63

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 3

M1 - e202316719

ER -

ID: 51604236