Standard

Fragmentary Model of the Atomic Structure of the Ion-Conducting Semiconductor Glass AgGeAsSe3. / Aleinikova, K.; Zinchenko, E.; Melnikova, N.
In: Glass Physics and Chemistry, Vol. 49, No. 5, 01.10.2023, p. 421-430.

Research output: Contribution to journalArticlepeer-review

Harvard

APA

Vancouver

Aleinikova K, Zinchenko E, Melnikova N. Fragmentary Model of the Atomic Structure of the Ion-Conducting Semiconductor Glass AgGeAsSe3. Glass Physics and Chemistry. 2023 Oct 1;49(5):421-430. doi: 10.1134/S1087659623600497

Author

Aleinikova, K. ; Zinchenko, E. ; Melnikova, N. / Fragmentary Model of the Atomic Structure of the Ion-Conducting Semiconductor Glass AgGeAsSe3. In: Glass Physics and Chemistry. 2023 ; Vol. 49, No. 5. pp. 421-430.

BibTeX

@article{29fada6ddee0468ebd7be3d73d3cc3bd,
title = "Fragmentary Model of the Atomic Structure of the Ion-Conducting Semiconductor Glass AgGeAsSe3",
abstract = "The atomic radial distribution function of vitreous AgGeAsSe3, obtained based on the experimental intensity curves taken with monochromatic copper and molybdenum radiation, is interpreted using a fragmentary model in the entire ordering region (~9 {\AA}). It is shown that the glass consists of selenium and selenium-arsenic tetrahedra with germanium and silver atoms inside. The spatial arrangement of such tetrahedra in glass within the ordering region is similar to their arrangement in the GeAsSe and GeSe2 structures. It is proposed that the “openwork” structure of the fragments of these structures allows the movement of Ag+ ions (ionic conductivity) in vitreous AgGeAsSe3. Fragments of the structure of the ion-conducting compound Ag2Se are not found in the studied glass.",
author = "K. Aleinikova and E. Zinchenko and N. Melnikova",
year = "2023",
month = oct,
day = "1",
doi = "10.1134/S1087659623600497",
language = "English",
volume = "49",
pages = "421--430",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "5",

}

RIS

TY - JOUR

T1 - Fragmentary Model of the Atomic Structure of the Ion-Conducting Semiconductor Glass AgGeAsSe3

AU - Aleinikova, K.

AU - Zinchenko, E.

AU - Melnikova, N.

PY - 2023/10/1

Y1 - 2023/10/1

N2 - The atomic radial distribution function of vitreous AgGeAsSe3, obtained based on the experimental intensity curves taken with monochromatic copper and molybdenum radiation, is interpreted using a fragmentary model in the entire ordering region (~9 Å). It is shown that the glass consists of selenium and selenium-arsenic tetrahedra with germanium and silver atoms inside. The spatial arrangement of such tetrahedra in glass within the ordering region is similar to their arrangement in the GeAsSe and GeSe2 structures. It is proposed that the “openwork” structure of the fragments of these structures allows the movement of Ag+ ions (ionic conductivity) in vitreous AgGeAsSe3. Fragments of the structure of the ion-conducting compound Ag2Se are not found in the studied glass.

AB - The atomic radial distribution function of vitreous AgGeAsSe3, obtained based on the experimental intensity curves taken with monochromatic copper and molybdenum radiation, is interpreted using a fragmentary model in the entire ordering region (~9 Å). It is shown that the glass consists of selenium and selenium-arsenic tetrahedra with germanium and silver atoms inside. The spatial arrangement of such tetrahedra in glass within the ordering region is similar to their arrangement in the GeAsSe and GeSe2 structures. It is proposed that the “openwork” structure of the fragments of these structures allows the movement of Ag+ ions (ionic conductivity) in vitreous AgGeAsSe3. Fragments of the structure of the ion-conducting compound Ag2Se are not found in the studied glass.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85177041740

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001104736100009

U2 - 10.1134/S1087659623600497

DO - 10.1134/S1087659623600497

M3 - Article

VL - 49

SP - 421

EP - 430

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 5

ER -

ID: 48507773