Research output: Contribution to journal › Conference article › peer-review
Research output: Contribution to journal › Conference article › peer-review
}
TY - JOUR
T1 - Effect of hydrostatic and chemical pressure on BaF2 and BaF2 : Eu2+ crystals
AU - Nikiforov, A.
AU - Zakharov, A.
AU - Chernyshev, V.
AU - Ougryumov, M.
AU - Kotomanov, S.
N1 - This study was supported by the Ministry of Education (project no. E00-3.4-227) and CRDF (grant no. REC 005).
PY - 2002
Y1 - 2002
N2 - The effect of hydrostatic pressure on a BaF2 crystal was studied within the shell model in the pairwise potential approximation. The structural phase transition from the cubic to orthorhombic phase was simulated. The behavior of the unit-cell parameters of the alpha- and beta-BaF2 phases under hydrostatic pressure (from 0 to 12 GPa) was investigated. The fundamental vibration frequencies of BaF2 under hydrostatic pressure (0-3.5 GPa) were calculated for both phases. The effect of chemical pressure on the BaF2 crystal was studied by simulating Ba1 - xMexF2 mixed crystals (Me = Ca, Sr). It was shown that at impurity concentrations up to 15-20 at. % the lattice constant varies in the same way as it does when hydrostatic pressure increases to P-c, which corresponds to a phase transition to the orthorhombic phase. The effect of chemical and hydrostatic pressure on BaF2 : Eu2+ doped crystals was also studied. The dependence of the absorption and luminescence zero-phonon line shift on the Eu2+-ligand distance was calculated. (C) 2002 MAIK "Nauka/Interperiodica".
AB - The effect of hydrostatic pressure on a BaF2 crystal was studied within the shell model in the pairwise potential approximation. The structural phase transition from the cubic to orthorhombic phase was simulated. The behavior of the unit-cell parameters of the alpha- and beta-BaF2 phases under hydrostatic pressure (from 0 to 12 GPa) was investigated. The fundamental vibration frequencies of BaF2 under hydrostatic pressure (0-3.5 GPa) were calculated for both phases. The effect of chemical pressure on the BaF2 crystal was studied by simulating Ba1 - xMexF2 mixed crystals (Me = Ca, Sr). It was shown that at impurity concentrations up to 15-20 at. % the lattice constant varies in the same way as it does when hydrostatic pressure increases to P-c, which corresponds to a phase transition to the orthorhombic phase. The effect of chemical and hydrostatic pressure on BaF2 : Eu2+ doped crystals was also studied. The dependence of the absorption and luminescence zero-phonon line shift on the Eu2+-ligand distance was calculated. (C) 2002 MAIK "Nauka/Interperiodica".
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000178374400020
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=0036807063
U2 - 10.1134/1.1514786
DO - 10.1134/1.1514786
M3 - Conference article
VL - 44
SP - 1949
EP - 1953
JO - Physics of the Solid State
JF - Physics of the Solid State
SN - 1063-7834
IS - 10
ER -
ID: 43720980