Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Correlation of standard and conventional standard redox potentials in molten chlorides
AU - Lebedev, V. A.
PY - 1994
Y1 - 1994
N2 - As shown on the base of literature data, the relation between standard (Em/n°) and conventional standard (Em/n×) potentials of the metal forming ions Mem+ and Men+ in molten halogenides is unambiguously defined by the ratio of ionic moments of solute and solvent salts cations. The equation is derived that makes it possible to calculate true values of standard redox potentials using experimental data on (Em/n×) in various salt solvents. The latter help in solution of important theoretical and practical problems of electrochemistry related to the stability of valent state of ions being in contact with metals and alloys in salt solvents.
AB - As shown on the base of literature data, the relation between standard (Em/n°) and conventional standard (Em/n×) potentials of the metal forming ions Mem+ and Men+ in molten halogenides is unambiguously defined by the ratio of ionic moments of solute and solvent salts cations. The equation is derived that makes it possible to calculate true values of standard redox potentials using experimental data on (Em/n×) in various salt solvents. The latter help in solution of important theoretical and practical problems of electrochemistry related to the stability of valent state of ions being in contact with metals and alloys in salt solvents.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=0028684641
M3 - Статья
VL - 339
SP - 493
EP - 495
JO - Doklady akademii nauk sssr
JF - Doklady akademii nauk sssr
SN - 0002-3264
IS - 4
ER -
ID: 55159419