Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Adsorption of Cr(VI) by Nanosized Rutile under the Action of UV Radiation
AU - Pechishcheva, N. V.
AU - Ordinartsev, D. P.
AU - Valeeva, A. A.
AU - Zaitseva, P.
AU - Korobitsyna, A. D.
AU - Sushnikova, A. A.
AU - Kim, A. V.
AU - Shunyaev, K. Yu.
AU - Rempel’, A. A.
N1 - This study was financially supported by the Russian Science Foundation (project no. 21-73-20039). It was performed using the equipment of the Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, and the Ural-M Multiaccess Center. The team of authors is grateful to A.V. Varaksin for help in determining the specific surface areas and to S.A. Petrova for determining the phase composition of the sorbents.
PY - 2023/2/1
Y1 - 2023/2/1
N2 - The properties of nanosized sorbents prepared by high-energy milling from microcrystalline powder of titanium dioxide of rutile modification have been studied. It was established that milling to an average crystallite size of ~30 nm and ultraviolet illumination significantly improved the sorption properties of rutile with respect to chromium compared with those of the starting material and the ability of Cr(VI) to be reduced to Cr(III) in its presence. The maximum removal of Cr(VI) from aqueous solutions with a concentration of 50 mg/L was achieved under UV illumination in an acetate buffer medium at pH 4–5 and a content of ground rutile of 16.7 g/L. A mechanism of adsorption was proposed.
AB - The properties of nanosized sorbents prepared by high-energy milling from microcrystalline powder of titanium dioxide of rutile modification have been studied. It was established that milling to an average crystallite size of ~30 nm and ultraviolet illumination significantly improved the sorption properties of rutile with respect to chromium compared with those of the starting material and the ability of Cr(VI) to be reduced to Cr(III) in its presence. The maximum removal of Cr(VI) from aqueous solutions with a concentration of 50 mg/L was achieved under UV illumination in an acetate buffer medium at pH 4–5 and a content of ground rutile of 16.7 g/L. A mechanism of adsorption was proposed.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85156117175
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000979071100015
U2 - 10.1134/S0036024423020206
DO - 10.1134/S0036024423020206
M3 - Article
VL - 97
SP - 392
EP - 396
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 2
ER -
ID: 38481158