The absorption spectra of cobalt-doped anatase TiO_2 nanopowders in the infrared and visible ranges have been studied after various oxidative and reductive treatments. The annealing leads to the appearance of the Drude-like contribution in the infrared region and significant change in the absorption in an visible range due to the formation of defects of the oxygen-vacancy-type and Ti^3+ ions. The observed additional contribution in the absorption spectra of TiO_2:Co nanopowders as compared to the spectra of undoped powders is ascribed to the d – d transitions in ions Co^2+. The change in the absorption related to cobalt after annealing is explained by a change in the local environment of Co ions from the octahedral to the tetrahedral environment.
Translated title of the contributionOptical Properties of a Nanocrystalline Co-Doped TiO2 after Various Treatments
Original languageRussian
Pages (from-to)994-1000
Number of pages7
JournalФизика твердого тела
Volume61
Issue number5
DOIs
Publication statusPublished - 2019

    GRNTI

  • 29.00.00 PHYSICS

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