(4-Fluorobenzyl)triphenylphosphonium dicyanodihaloaurates [Ph3PCH2C6H4F-4][Au(CN)2Hlg2], Hlg = Cl, Br, I, were synthesized from (4-fluorobenzyl)triphenylphosphonium chloride and potassium dicyanodihaloaurate in water. Structure of the compounds was characterized by IR, 1H, 13C {1H} and 19F {1H} NMR spectroscopy, elemental analysis and X-ray structural analysis. According to X-ray diffraction data, complexes obtained contain tetrahedral (4-fluorobenzyl)triphenylphosphonium cations and two types of square centrosymmetric [Au(CN)2Hlg2]- anions.
Translated title of the contributionSYNTHESIS AND STRUCTURE OF (4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUM DICYANODIHALOAURATES [PH3PCH2C6H4F-4][AU(CN)2HLG2]
Original languageRussian
Pages (from-to)1716-1722
Number of pages7
JournalЖурнал общей химии
Volume91
Issue number11
DOIs
Publication statusPublished - 2021

    Level of Research Output

  • VAK List
  • Russian Science Citation Index

    GRNTI

  • 31.00.00 CHEMISTRY

ID: 28966958