The growth of effectiveness has been shown in the gas phase luminicence of naproxene-containing 3-aryl-6-indolyl-1,2,4-triazine-5-(4H)-ones, as well as 1,4-disubstituted pentipticenes at the interaction with polynitrocontaining compounds (TATB, TNT, picric acid, dinitrotoluene) through obtaining on their basis nanofibrous materials using electrospinning procedure (electromolding). We worked out the conditions for conducting electrospinning to obtain the materials with relevant properties.