The paper considers a method used to determine Faraday current efficiency ( Ce F) based on the ratio of partial currents of metal and hydrogen reduction. To calculate the Faraday current efficiency based on polarization measurements, it is necessary to know the working current density and potential ( E i) at which the metal is deposited in the corresponding solution, as well as kinetic parameters of hydrogen evolution for determining the partial current density of hydrogen ( i H2to calculate current efficiency for the processes of nickel extraction and nickel coating application from solutions containing nickel sulfate at current density of 300 A/m2. The study allowed to determine kinetic parameters of hydrogen evolution by the polarization curve obtained in the background electrolyte solution containing 120 g/l of magnesium sulfate and 18 g/l of boric acid at pH = 3.9. An equation was obtained to calculate the partial current density of hydrogen evolution at any potential by kinetic parameters. The use of kinetic regularities made it possible to calculate nickel Ce F in sulphate solutions of different composition and with different pH values (3.0 and 4.1). The calculated Ce F values within the margin of error coincide with the current efficiency value determined by the gravimetric method using a copper coulometer. It is shown that the division of the «total current efficiency» ( Ce Σ), which is acommercial indicator, into Faraday ( Ce F) and apparatus ( Ce ap) indicators in combination with the method using partial polarization provide additional information about the degree of process perfection.
Translated title of the contributionApplication of polarization measurements for current efficiency calculation
Original languageRussian
Pages (from-to)32-39
Number of pages8
JournalИзвестия высших учебных заведений. Цветная металлургия
Issue number5
DOIs
Publication statusPublished - 2019

    Level of Research Output

  • VAK List

    GRNTI

  • 61.13.00

ID: 11245617